Structural effects on ethanol oxidation on Pt nanoparticles with different shapes and surface structures

• Grant number: 12/01040-3
• Support Opportunities: Scholarships abroad - Research Internship - Master's degree
• Effective date (Start): September 01, 2012
• Effective date (End): November 30, 2012
• Field of knowledge: Physical Sciences and Mathematics - Chemistry - Physical-Chemistry
• Principal Investigator: Hebe de las Mercedes Villullas
• Grantee: Nathalia Abe Santos
• Supervisor: Juan Miguel Feliu Martinez
• Host Institution: Instituto de Química (IQ). Universidade Estadual Paulista (UNESP). Campus de Araraquara. Araraquara , SP, Brazil
• Research place: Universidad de Alicante (UA), Spain
• Associated to the scholarship: 10/13733-8 - New strategies in the study of ethanol electrooxidation: multimetallic nanocatalysts and analysis of reaction products, BP.MS

Abstract

The current catalysts for ethanol oxidation in fuel cells are not efficient enough to make possible the use of these devices for large scale energy generation. At the same time, the tailoring of more efficient catalysts requires a deeper understanding of the influence that the materials properties have on catalytic activity and reaction mechanisms. This research project involves the preparation of Pt nanoparticles with different shapes and surface structures with the purpose of comparing the relative importance of these two properties on the catalytic activity towards ethanol oxidation. This proposal includes: i) the use of nanoparticles with different shapes having surfaces with (111) (octahedrons e tetrahedrons), ii) the controlled introduction of (100) e (110) surface defects; iii) the comparative evaluation of the catalytic activity towards the oxidation of ethanol by studies combining the current/potential responses obtained by cyclic voltammetry with the determination of gaseous and volatile products by differential electrochemical mass spectroscopy (DEMS). The proposed strategy aims to establish correlations between the catalytic responses towards ethanol oxidation of extended well-defined surfaces of single crystal electrodes and those of nanoparticles with different shapes and surface structures, aiming a deeper understanding of structural effects as a way to contribute to the development of efficient anode materials for Direct Alcohol Fuel Cells. (AU)