NMR study of the magneto-convective phenomenon on paramagnetic ions during electrodeposition

• Grant number: 12/22281-9
• Support Opportunities: Scholarships in Brazil - Doctorate (Direct)
• Start date: July 01, 2013
• End date: February 28, 2018
• Field of knowledge: Physical Sciences and Mathematics - Chemistry - Analytical Chemistry
• Principal Investigator: Luiz Alberto Colnago
• Grantee: Bruna Ferreira Gomes Lobo
• Host Institution: Embrapa Instrumentação Agropecuária. Empresa Brasileira de Pesquisa Agropecuária (EMBRAPA). São Carlos , SP, Brazil
• Associated scholarship(s): 16/01537-6 - Study of the coupling between electrochemistry and low-field, mid-resolution NMR for the in situ and on line analysis of redox reactions of organic compounds and the evaluation of the magnetic field effect on the velocity of the in situ reactions, BE.EP.DD

Abstract

The electrodeposition has been widely studied due to the demonstration that the magnetic field can be used to change the electrodeposition, controlling the morphology of electrodeposited films or mass transport of reactants towards the electrodes and also the rate of reaction in the electrode / electrolyte interface. The term magnetoelectrolysis refers to the different ways in which the magnetic field influences an electrochemical process. As we recently demonstrated that time domain nuclear magnetic resonance (TD-NMR) can be an important analytical tool for the study of electrodeposition of paramagnetic ions in solution, we intend to use it to study the magnetic electrolysis phenomenon in situ, using the NMR magnet to induce magnetic convections. For this it will necessary : the construction of electrochemical cells for in situ analysis with TD-NMR; studies of in situ electrodeposition reactions of paramagnetic ions, Cu 2 +, Ni +2, Cr 3 +, Mn +2; studies of the effect of magnetic fields parallel and perpendicular to the working electrode in electrodeposition reaction of paramagnetic ions, the study of electrodeposition reaction in the presence of a magnetic field gradient of unilateral NMR spectrometer and the theoretical / experimental study of magneto-convective forces in electrochemical experiments / TD-NMR. (AU)

Scientific publications

(13)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

GOMES, BRUNA FERREIRA; DA SILVA BURATO, JULIANA SOARES; SILVA LOBO, CARLOS MANUEL; COLNAGO, LUIZ ALBERTO. Use of the Relaxometry Technique for Quantification of Paramagnetic Ions in Aqueous Solutions and a Comparison with Other Analytical Methods. INTERNATIONAL JOURNAL OF ANALYTICAL CHEMISTRY, 2016. (12/22281-9)

BENDERS, STEFAN; GOMES, BRUNA FERREIRA; CARMO, MARCELO; COLNAGO, LUIZ ALBERTO; BLUEMICH, BERNHARD. In-situ MRI velocimetry of the magnetohydrodynamic effect in electrochemical cells. JOURNAL OF MAGNETIC RESONANCE, v. 312, MAR 2020. (12/22281-9, 17/12864-0, 16/01537-6)

LOBO, CARLOS M. S.; GOMES, BRUNA F.; BOUZOUMA, HAJAR; DANIELI, ERNESTO; BLUEMICH, BERNHARD; COLNAGO, LUIZ A.. Improving in operando low field NMR copper electrodeposition analyses using inductively coupled coils. Electrochimica Acta, v. 298, p. 844-851, MAR 1 2019. (17/12864-0, 12/22281-9, 16/01537-6)

DA SILVA, POLLYANA FERREIRA; GOMES, BRUNA FERREIRA; SILVA LOBO, CARLOS MANUEL; CARMO, MARCELO; ROTH, CHRISTINA; COLNAGO, LUIZ ALBERTO. Composite Graphite-Epoxy Electrodes for In Situ Electrochemistry Coupling with High Resolution NMR. ACS OMEGA, v. 7, n. 6, p. 10-pg., 2022-01-31. (21/12694-3, 19/13656-8, 12/22281-9)

NASCIMENTO MITRE, CIRLEI IGREJA; GOMES, BRUNA FERREIRA; PARIS, ELAINE; SILVA LOBO, CARLOS MANUEL; ROTH, CHRISTINA; COLNAGO, LUIZ ALBERTO. Use of Time Domain Nuclear Magnetic Resonance Relaxometry to Monitor the Effect of Magnetic Field on the Copper Corrosion Rate in Real Time. MAGNETOCHEMISTRY, v. 8, n. 4, p. 10-pg., 2022-04-01. (21/12694-3, 19/13656-8, 12/22281-9)

GOMES, BRUNA FERREIRA; SILVA LOBO, CARLOS MANUEL; COLNAGO, LUIZ ALBERTO. Monitoring Electrochemical Reactions in Situ with Low Field NMR: A Mini-Review. APPLIED SCIENCES-BASEL, v. 9, n. 3, FEB 1 2019. (16/01537-6, 17/12864-0, 12/22281-9)

GOMES, BRUNA FERREIRA; SILVA NUNES, LUIZA MARIA; SILVA LOBO, CARLOS MANUEL; CABECA, LUIS FERNANDO; COLNAGO, LUIZ ALBERTO. In Situ Study of the Magnetoelectrolysis Phenomenon during Copper Electrodeposition Using Time Domain NMR Relaxometry. Analytical Chemistry, v. 86, n. 19, p. 9391-9393, OCT 7 2014. (07/07436-8, 12/22281-9)

DA SILVA, POLLYANA FERREIRA; GOMES, BRUNA FERREIRA; SILVA LOBO, CARLOS MANUEL; KENG QUEIROZ JUNIOR, LUIZ HENRIQUE; DANIELI, ERNESTO; CARMO, MARCELO; BLUEMICH, BERNHARD; COLNAGO, LUIZ ALBERTO. Electrochemical NMR spectroscopy: Electrode construction and magnetic sample stirring. Microchemical Journal, v. 146, p. 658-663, MAY 2019. (17/12864-0, 12/22281-9, 16/01537-6)

GOMES, B. F.; NUNES, L. M. S.; LOBO, C. M. S.; CARVALHO, A. S.; CABECA, L. F.; COLNAGO, L. A.. In situ analysis of copper electrodeposition reaction using unilateral NMR sensor. JOURNAL OF MAGNETIC RESONANCE, v. 261, p. 83-86, DEC 2015. (07/07436-8, 12/22281-9)

GOMES, BRUNA FERREIRA; DA SILVA, POLLYANA FERREIRA; SILVA LOBO, CARLOS MANUEL; SANTOS, MAIARA DA SILVA; COLNAGO, LUIZ ALBERTO. Strong magnetoelectrolysis effect during electrochemical reaction monitored in situ by high-resolution NMR spectroscopy. Analytica Chimica Acta, v. 983, p. 91-95, AUG 29 2017. (12/22281-9)

COBRA, PAULO FALCO; GOMES, BRUNA FERREIRA; NASCIMENTO MITRE, CIRLEI IGREJA; BARBOSA, LUCIO LEONE; MARCONCINI, LUCINEIA VIZZOTTO; COLNAGO, LUIZ ALBERTO. Measuring the solubility product constant of paramagnetic cations using time-domain nuclear magnetic resonance relaxometry. Microchemical Journal, v. 121, p. 14-17, JUL 2015. (12/22281-9, 12/20247-8)

GOMES, BRUNA FERREIRA; HOLZHAEUSER, FABIAN JOSCHKA; SILVA LOBO, CARLOS MANUEL; DA SILVA, POLLYANA FERREIRA; DANIELI, ERNESTO; CARMO, MARCELO; COLNAGO, LUIZ ALBERTO; PALKOVITS, STEFAN; PALKOVITS, REGINA; BLUEMICH, BERNHARD. Sustainable Electrocoupling of the Biogenic Valeric Acid under in Situ Low-Field Nuclear Magnetic Resonance Conditions. ACS SUSTAINABLE CHEMISTRY & ENGINEERING, v. 7, n. 22, p. 18288-18296, NOV 18 2019. (12/22281-9, 16/01537-6)

GOMES, BRUNA FERREIRA; DA SILVA BURATO, JULIANA SOARES; SILVA LOBO, CARLOS MANUEL; COLNAGO, LUIZ ALBERTO. Use of the Relaxometry Technique for Quantification of Paramagnetic Ions in Aqueous Solutions and a Comparison with Other Analytical Methods. INTERNATIONAL JOURNAL OF ANALYTICAL CHEMISTRY, v. 2016, p. 5-pg., 2016-01-01. (12/22281-9)

Academic Publications

(References retrieved automatically from State of São Paulo Research Institutions)

LOBO, Bruna Ferreira Gomes. Magnetoelectrolysis study during the NMR-Electrochemistry in situ coupling. 2018. Doctoral Thesis - Universidade de São Paulo (USP). Instituto de Química de São Carlos (IQSC/BT) São Carlos.