Degradation of hair dyes and salon wastewater by photoelectrocatalysis with modified TiO2 nanotube electrodes and combination with ozonation

• Grant number: 14/03679-7
• Support Opportunities: Scholarships in Brazil - Doctorate (Direct)
• Start date: June 01, 2014
• End date: February 28, 2017
• Field of knowledge: Physical Sciences and Mathematics - Chemistry - Analytical Chemistry
• Principal Investigator: Maria Valnice Boldrin
• Grantee: Guilherme Garcia Bessegato
• Host Institution: Instituto de Química (IQ). Universidade Estadual Paulista (UNESP). Campus de Araraquara. Araraquara , SP, Brazil
• Associated research grant: 08/10449-7 - Assessment of occurrence, toxicity/genotoxicity and degradation processes of dyes in effluents and surface water, AP.TEM
• Associated scholarship(s): 15/00822-6 - Synthesis and characterization of Si/TiO2/Au composite anodes for a novel synthetic approach to fluorinated pharmaceuticals and dye degradation, BE.EP.DD

Abstract

The hair dyeing process is complex and involves multiple components with different functions, producing an effluent with a high organic load and questionable toxicity/ mutagenicity. This project aims to continue the FAPESP process 2012/18357-0 that investigates the application of boron-doped and Sb2S3 modified TiO2 nanotubes (TiO2 NTs) applied in the photoelectrocatalytic treatment of temporary hair dye. Basic Red 51, Basic Blue 99 and Acid Yellow 1 were chosen as hair dyes models for treatment, owing different functional groups. We also intend to study the combination of photoelectrocatalysis technique with ozonation for wastewater treatment of highly colored beauty salon. Thus, we intend to develop an alternative methodology of high efficiency for hair dyes and salon effluent treatment in comparison with standard techniques, since the literature does not present any work of combination of photoelectrocatalysis with ozonation. (AU)

Scientific publications

(15)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

BESSEGATO, GUILHERME G.; DE ALMEIDA, LUCIO C.; FERREIRA, SERGIO L. C.; BOLDRIN ZANONI, MARIA VALNICE. Experimental design as a tool for parameter optimization of photoelectrocatalytic degradation of a textile dye. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, v. 7, n. 4, AUG 2019. (08/10449-7, 11/21606-9, 14/50945-4, 15/18109-4, 12/18357-0, 14/03679-7)

DE SOUZA, JOAO CARLOS; DA SILVA, BIANCA FERREIRA; MORALES, DANIEL ALEXANDRE; UMBUZEIRO, GISELA DE ARAGAO; BOLDRIN ZANONI, MARIA VALNICE. Assessment of the autoxidation mechanism of p-toluenediamine by air and hydrogen peroxide and determination of mutagenic environmental contaminant in beauty salon effluent. Science of The Total Environment, v. 685, p. 911-922, OCT 1 2019. (15/12998-1, 14/03679-7)

FRANCO, JEFFERSON HONORIO; BEN AISSA, ALEJANDRA; BESSEGATO, GUILHERME GARCIA; MARTINEZ FAJARDO, LAURA; BOLDRIN ZANONI, MARIA VALNICE; ISABEL PIVIDORI, MARIA; TABOADA SOTOMAYOR, MARIA DEL PILAR. Assessment of molecularly imprinted polymers (MIPs) in the preconcentration of disperse red 73 dye prior to photoelectrocatalytic treatment. Environmental Science and Pollution Research, v. 24, n. 4, p. 4134-4143, FEB 2017. (14/03679-7, 14/25264-3)

BESSEGATO, GUILHERME GARCIA; HUDARI, FELIPE FANTINATO; BOLDRIN ZANONI, MARIA VALNICE. Self-doped TiO2 nanotube electrodes: A powerful tool as a sensor platform for electroanalytical applications. Electrochimica Acta, v. 235, p. 527-533, MAY 1 2017. (15/18109-4, 14/03679-7)

USUKURA KIM, JOAQUIM YUJI; BESSEGATO, GUILHERME G.; DE SOUZA, BARBARA C.; DA SILVA, JOSIEL J.; BOLDRIN ZANONI, MARIA VALNICE. Efficient treatment of swimming pool water by photoelectrocatalytic ozonation: Inactivation of Candida parapsilosis and mineralization of Benzophenone-3 and urea. CHEMICAL ENGINEERING JOURNAL, v. 378, DEC 15 2019. (15/18109-4, 14/03679-7)

DE BRITO, JULIANA FERREIRA; BESSEGATO, GUILHERME GARCIA; FRAGA DE TOLEDO E SOUZA, PEDRO RAFAEL; VIANA, TAIS SUELEN; DE OLIVEIRA, DANIELLE PALMA; MARTINEZ-HUITLE, CARLOS ALBERTO; BOLDRIN ZANONI, MARIA VALNICE. Combination of Photoelectrocatalysis and Ozonation as a Good Strategy for Organics Oxidation and Decreased Toxicity in Oil-Produced Water. Journal of the Electrochemical Society, v. 166, n. 5, p. H3231-H3238, FEB 12 2019. (14/03679-7, 15/18109-4, 14/50945-4, 13/25343-8)

BESSEGATO, GUILHERME GARCIA; DE SOUZA, JOAO CARLOS; CARDOSO, JULIANO CARVALHO; BOLDRIN ZANONI, MARIA VALNICE. Assessment of several advanced oxidation processes applied in the treatment of environmental concern constituents from a real hair dye wastewater. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, v. 6, n. 2, p. 2794-2802, APR 2018. (14/03679-7, 15/18109-4, 15/12998-1)

RAJESHWAR, KRISHNAN; VALI, ABBAS; DE BRITO, JULIANA FERREIRA; BOLDRIN ZANONI, MARIA VALNICE. Naming Photoelectrochemical Processes: Why Thermodynamics Holds the Key. ACS ENERGY LETTERS, v. 6, n. 6, p. 4-pg., 2021-05-18. (14/50945-4, 15/18109-4, 14/03679-7, 18/02950-0, 13/25343-8)

DE BRITO, JULIANA FERREIRA; BESSEGATO, GUILHERME GARCIA; LIMA PERINI, JOAO ANGELO; DE MOURA TORQUATO, LILIAN DANIELLE; BOLDRIN ZANONI, MARIA VALNICE. Advances in photoelectroreduction of CO2 to hydrocarbons fuels: Contributions of functional materials. JOURNAL OF CO2 UTILIZATION, v. 55, JAN 2022. (14/03679-7, 13/25343-8, 16/18057-7, 14/50945-4, 18/02950-0, 19/00463-7, 15/18109-4)

HUDARI, FELIPE F.; BESSEGATO, GUILHERME G.; BEDATTY FERNANDES, FLAVIO C.; ZANONI, MARIA V. B.; BUENO, PAULO R.. Reagentless Detection of Low-Molecular-Weight Triamterene Using Self-Doped TiO2 Nanotubes. Analytical Chemistry, v. 90, n. 12, p. 7651-7658, JUN 19 2018. (15/13359-2, 15/18109-4, 14/03679-7, 12/22820-7)

DE SOUZA, JOAO CARLOS; DA SILVA, JOSE LUIZ; FABRAO, RODRIGO MONTEIRO; STRADIOTTO, NELSON RAMOS; BOLDRIN ZANONI, MARIA VALNICE. Electroactive sugars, organic acids and sugar alcohol analysis in wine using anion-exchange chromatography with electrochemical detection. Microchemical Journal, v. 147, p. 972-978, JUN 2019. (14/03679-7, 15/12998-1)

BESSEGATO, G. G.; COOKE, M. D.; CHRISTENSEN, P. A.; WOOD, D.; ZANONI, M. V. B.. Synthesis and electrochemical characterization of Si/TiO2/Au composite anode: Efficient oxygen evolution and hydroxyl radicals generation. Electrochimica Acta, v. 370, FEB 20 2021. (15/00822-6, 14/03679-7, 12/18357-0)

BESSEGATO, GUILHERME GARCIA; CARDOSO, JULIANO CARVALHO; DA SILVA, BIANCA FERREIRA; BOLDRIN ZANONI, MARIA VALNICE. Combination of photoelectrocatalysis and ozonation: A novel and powerful approach applied in Acid Yellow 1 mineralization. APPLIED CATALYSIS B-ENVIRONMENTAL, v. 180, p. 161-168, JAN 2016. (14/03679-7, 08/10449-7)

CARDOSO, JULIANO CARVALHO; BESSEGATO, GUILHERME GARCIA; BOIDRIN ZANONI, MARIA VALNICE. Efficiency comparison of ozonation, photolysis, photocatalysis and photoelectrocatalysis methods in real textile wastewater decolorization. WATER RESEARCH, v. 98, p. 39-46, JUL 1 2016. (14/03679-7, 15/18109-4)

MARTINS, ALYSSON STEFAN; MARQUES CORDEIRO-JUNIOR, PAULO JORGE; BESSEGATO, GUILHERME GARCIA; CARNEIRO, JUSSARA FERNANDES; BOLDRIN ZANONI, MARIA VALNICE; DE VASCONCELOS LANZA, MARCOS ROBERTO. Electrodeposition of WO3 on Ti substrate and the influence of interfacial oxide layer generated in situ: A photoelectrocatalytic degradation of propyl paraben. Applied Surface Science, v. 464, p. 664-672, JAN 15 2019. (14/03679-7, 13/08543-3, 17/13123-4, 17/10118-0)