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Exploring the ACDC concept on hydrogenation and Friedel-Crafts reactions using indolizines obtained from Morita-Baylis-Hillman adducts

Grant number: 14/02062-6
Support type:Scholarships abroad - Research Internship - Doctorate
Effective date (Start): January 12, 2015
Effective date (End): January 11, 2016
Field of knowledge:Physical Sciences and Mathematics - Chemistry - Organic Chemistry
Principal researcher:Fernando Antonio Santos Coelho
Grantee:José Tiago Menezes Correia
Supervisor abroad: Benjamin List
Home Institution: Instituto de Química (IQ). Universidade Estadual de Campinas (UNICAMP). Campinas , SP, Brazil
Research place: Max Planck Society, Mulheim, Germany  
Associated to the scholarship:12/21809-0 - Organocatalysed synthesis of indolizidinic and quinolizidinic N-heterocycles from Morita-Baylis-Hillman adducts, BP.DR

Abstract

The project consists on a methodological study of two transformations involving Indolizines obtained from Morita-Baylis-Hillman adducts. They are: an asymmetric transfer hydrogenation reaction and an asymmetric Friedel-Crafts alkylation , both catalyzed by chiral phosphoric acids derived from BINOL. The Indolizines are interesting building blocks, since they can be converted to compounds endowed with biological activity and to indolizidinic alkaloids. (AU)

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Scientific publications
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
MENEZES CORREIA, JOSE TIAGO; LIST, BENJAMIN; COELHO, FERNANDO. Catalytic Asymmetric Conjugate Addition of Indolizines to alpha,beta-Unsaturated Ketones. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v. 56, n. 27, p. 7967-7970, JUN 26 2017. Web of Science Citations: 23.

Please report errors in scientific publications list by writing to: cdi@fapesp.br.