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Green photochemistry: development of transition metal complexes for activation of luminescent singlet oxygen and its application in the disinfection of wastewaters contaminated with pathogenic microorganisms (Escherichia coli and Enterococcus faecalis)

Grant number: 14/17476-0
Support type:Scholarships abroad - Research Internship - Doctorate
Effective date (Start): November 07, 2014
Effective date (End): June 12, 2015
Field of knowledge:Physical Sciences and Mathematics - Chemistry - Inorganic Chemistry
Principal Investigator:Rose Maria Carlos
Grantee:Paulo José de Sousa Maia
Supervisor abroad: Matthias Selke
Home Institution: Centro de Ciências Exatas e de Tecnologia (CCET). Universidade Federal de São Carlos (UFSCAR). São Carlos , SP, Brazil
Local de pesquisa : California State University, Los Angeles, United States  
Associated to the scholarship:12/09449-8 - Photochemistry "green": development of transition metal complexes for activation of luminescent singlet oxygen ánd its application ín “The disinfection of water contaminated with pathogenic microorganisms (Escherichia coli ánd Enterococcus faecalis), BP.DR


In this project we intend to develop luminescent transition metals to act as photocatalysts for disinfection of water contaminated with pathogenic microorganisms. ¬The system was planned to work in rural and/or in small communities of poor sanitation, where lack of infrastructure, funding for operating expenses, plus the lack of training of users limit the use of conventional technologies such as chlorination, ozone, UV radiation. Considering these conditions, we propose a self-sustaining system which uses only water and sunlight as energy source and a luminescent transition metal complex to activate the singlet molecular oxygen, 1O2, formation. Upon exposure to visible light, the fotosensitizer catalyzes the production of singlet oxygen from the dissolved oxygen in the water. Singlet oxygen is a potent disinfectant, known to disable a wide range of bacteria and viruses. It is noteworthy that 1O2 presents high reactivity and short lifetime (a few microseconds in water, which in no way represents any risk of toxicity except for those microorganisms in the immediate vicinity to the singlet oxygen photogeneration. We intend to prepare a series of luminescent complexes of the type [Ru(a-diimine)2(phen-per)3]2+ and evaluate their spectroscopic properties, electrochemical, photochemical and photophysical properties in aqueous solution and in polymer films (silicon, nafion and cellulose) in the presence and absence of 3O2. Moreover, because these compounds are easy to synthesize and are thermally and chemically stable, exhibits intense luminescence in the visible region, and are ease of obtaining derivatives and are immobilized on polymeric films. The practical application of the photocatalyst on the treatment of water contaminated with the microorganism E. Coli will also be investigated. The results of this trial will be compared with the SODIS desinfection method in the same experimental conditions. We expected that this research opens unew perspectives for the purification of water for residential use contaminated with pathogenic microorganisms. (AU)

Scientific publications
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
SOUSA MAIA, PAULO JOSE; DE AGUIAR, INARA; VELLOSO, MARISOL DOS SANTOS; ZHANG, DONG; DOS SANTOS, EDJANE ROCHA; DE OLIVEIRA, JONATAS RAFAEL; JUNQUEIRA, JULIANA CAMPOS; SELKE, MATTHIAS; CARLOS, ROSE MARIA. Singlet oxygen production by a polypyridine ruthenium (II) complex with a perylene monoimide derivative: A strategy for photodynamic inactivation of Candida albicans. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, v. 353, p. 536-545, FEB 15 2018. Web of Science Citations: 4.

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