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Nanostructured sensors modified with graphene and tapioca for determination of phenolics compounds and nitrogenous bases

Grant number: 16/12697-4
Support Opportunities:Scholarships in Brazil - Scientific Initiation
Start date: August 01, 2016
End date: December 31, 2019
Field of knowledge:Physical Sciences and Mathematics - Chemistry - Analytical Chemistry
Principal Investigator:Bruno Campos Janegitz
Grantee:Luiz Otávio Orzari
Host Institution: Centro de Ciências Agrárias (CCA). Universidade Federal de São Carlos (UFSCAR). Araras , SP, Brazil

Abstract

In recent years, the development of nanostructured sensors and biosensors has attracted great interest from scientific community, because they are cheap alternatives for the determination of various substances. In this context, we can highlight graphene, which has interesting physicochemical properties, such as high surface area, high electrical conductivity and strong mechanical resistance. Tapioca, in turn, has a high starch value in its composition, that along which its physical characteristics makes this material an excellent candidate for the nanomaterial support function, in its polymerized form, which can be utilized in modified electrodes. In the present work, are proposed new sensors architectures, using graphene and tapioca for the determination of phenolic compounds and nitrogenous bases adenine and guanine in biological samples, in order to develop systems with low cost and high sensibility.

News published in Agência FAPESP Newsletter about the scholarship:
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Scientific publications (6)
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
ORZARI, LUIZ OTAVIO; DE FREITAS, RAFAELA CRISTINA; DE ARAUJO ANDREOTTI, ISABELA APARECIDA; GATTI, ALEXANDRE; JANEGITZ, BRUNO CAMPOS. A novel disposable self-adhesive inked paper device for electrochemical sensing of dopamine and serotonin neurotransmitters and biosensing of glucose. BIOSENSORS & BIOELECTRONICS, v. 138, . (17/21898-6, 16/12697-4)
DE ARAUJO ANDREOTTI, ISABELA APARECIDA; ORZARI, LUIZ OTAVIO; CAMARGO, JESSICA ROCHA; FARIA, RONALDO CENSI; MARCOLINO-JUNIOR, LUIZ HUMBERTO; BERGARNINI, MARCIO FERNANDO; GATTI, ALEXANDRE; JANEGITZ, BRUNO C.. Disposable and flexible electrochemical sensor made by recyclable material and low cost conductive ink. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, v. 840, p. 109-116, . (17/21898-6, 16/12697-4, 18/02162-1)
ZAMBIANCO, NAIARA A.; DA SILVA, VINICIUS A. O. P.; ORZARI, LUIZ O.; CORAT, EVALDO J.; ZANIN, HUDSON G.; SILVA, TIAGO A.; BULLER, GARY A.; KEEFE, EDMUND M.; BANKS, CRAIG E.; JANEGITZ, BRUNO C.. Determination of tadalafil in pharmaceutical samples by vertically oriented multi-walled carbon nanotube electrochemical sensing device. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, v. 877, . (16/12697-4, 17/21097-3)
ORZARI, LUIZ OTAVIO; DE ARAUJO ANDREOTTI, ISABELA APARECIDA; BERGAMINI, MARCIO FERNANDO; MARCOLINO JUNIOR, LUIZ HUMBERTO; JANEGITZ, BRUNO CAMPOS. Disposable electrode obtained by pencil drawing on corrugated fiberboard substrate. SENSORS AND ACTUATORS B-CHEMICAL, v. 264, p. 20-26, . (16/12697-4, 15/19099-2)
ORZARI, LUIZ O.; SANTOS, FABRICIO A.; JANEGITZ, BRUNO C.. Manioc starch thin film as support of reduced graphene oxide: A novel architecture for electrochemical sensors. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, v. 823, p. 350-358, . (17/21898-6, 15/19099-2, 16/12697-4)
PRADEL-FILHO, LAURO A.; ANDREOTTI, ISABELA A. A.; CARVALHO, JEFFERSON H. S.; ARAUJO, DIELE A. G.; ORZARI, LUIZ O.; GATTI, ALEXANDRE; TAKEUCHI, REGINA M.; SANTOS, ANDRE L.; JANEGITZ, BRUNO C.. Glass varnish-based carbon conductive ink: A new way to produce disposable electrochemical sensors. SENSORS AND ACTUATORS B-CHEMICAL, v. 305, . (16/12697-4, 17/21898-6, 17/21097-3, 19/04085-7)

Filed patent(s) as a result of this research project

PROCESSO DE OBTENÇÃO DE FILME DE TAPIOCA PARA MODIFICAÇÃO DE ELETRODO DE CARBONO VÍTREO E PRODUTOS OBTIDOS BR1020180018230 - Universidade Federal de São Carlos (UFSCAR) . BRUNO CAMPOS JANEGITZ / GABRIELA CAROLINA MAURUTO DE OLIVEIRA / Kelly Roberta Francisco Muruci de Paula / LUIZ OTÁVIO ORZARI - January 2018, 29

DISPOSITIVOS ELETRÓDICOS ADESIVOS PARA APLICAÇÕES ELETROQUÍMICAS E MÉTODO DE OBTENÇÃO BR1020190090570 - Universidade Federal de São Carlos (UFSCAR) ; Universidade Federal do Paraná (UFPR) . BRUNO CAMPOS JANEGITZ ; JÉSSICA ROCHA CAMARGO ; ISABELA APARECIDA DE ARAUJO ANDREOTTI ; LUIZ OTÁVIO ORZARI ; MÁRCIO FERNANDO BERGAMINI ; LUIZ HUMBERTO MARCOLINO JUNIOR ; ALEXANDRE GATTI - May 2019, 03