Production and characterization of nanostructured binary and ternary composites of carbon fiber/graphene oxide/nickel oxide as high performance electrodes in supercapacitors

• Grant number: 17/05343-4
• Support Opportunities: Scholarships in Brazil - Doctorate
• Start date: October 01, 2017
• End date: December 31, 2021
• Field of knowledge: Engineering - Materials and Metallurgical Engineering - Nonmetallic Materials
• Principal Investigator: Neidenei Gomes Ferreira
• Grantee: André Ferreira Sardinha
• Host Institution: Instituto Nacional de Pesquisas Espaciais (INPE). São José dos Campos , SP, Brazil
• Associated scholarship(s): 19/22707-5 - Development of nanoporous metal electrodes functionalized with metal oxides, BE.EP.DR

Abstract

The growing demand for energy has stimulated research into energy storage and conversion systems. The International Energy Agency, for example, estimates that global energy demand will increase by about a third over the next twenty years [1]. Among these systems, supercapacitors have been outstanding due to their unique properties such as high power density, long life cycles and rapid loading-discharge [2, 3, 4]. In these systems, the electrodes are the most important parts in the search for their best performance and, therefore, the challenge is to obtain new composite materials, with high-energy efficiency. To this end, this project aims at the production and characterization of composites formed by Graphene Oxide (OG), Carbon Fiber (FC) and Nickel Oxide (NiO). First, two different OG syntheses will be performed, which will be reduced electrochemically on FC, forming the OGR/FC composite. Among these, the one with the best electrochemical response will be used in the next steps. Then, NiO synthesis will be performed, which will be calcined at different temperatures. The NiO obtained will be deposited on OGR/FC composites, which will be characterized morphologically by scanning electron microscopy and structurally by Raman scattering spectroscopy, X-ray diffraction and Fourier transform infrared spectroscopy. The electrochemical characterization will be studied by cyclic voltammetry, electrochemical impedance spectroscopy and charge/discharge tests. (AU)

Scientific publications

(The scientific publications listed on this page originate from the Web of Science or SciELO databases. Their authors have cited FAPESP grant or fellowship project numbers awarded to Principal Investigators or Fellowship Recipients, whether or not they are among the authors. This information is collected automatically and retrieved directly from those bibliometric databases.)

VERNASQUI, L. G.; SARDINHA, A. F.; OISHI, S. S.; FERREIRA, N. G.. Nanoscale control of high-quality boron-doped ultrananodiamond on dioxide titanium nanotubes as a porous composite. JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T, v. 12, p. 16-pg., 2021-03-22. (17/10118-0, 17/05343-4, 19/00592-1)

VERNASQUI, L. G.; SARDINHA, A. F.; OISHI, S. S.; FERREIRA, N. G.. anoscale control of high-quality boron-doped ultrananodiamond on dioxide titanium nanotubes as a porous composit. JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T, v. 12, p. 597-612, MAY-JUN 2021. (17/05343-4, 19/00592-1, 17/10118-0)

VERNASQUI, LAIS G. A.; KAWATA, BIANCA A.; SARDINHA, A. F. A.; RODRIGO, MANUEL A. G.; FERREIRA, NEIDENEI G.. Achievement and electrochemical responsiveness of advanced boron-doped ultrananocrystalline diamond on highly ordered titanium dioxide nanotubes. DIAMOND AND RELATED MATERIALS, v. 121, p. 11-pg., 2022-01-05. (17/05343-4, 19/00592-1, 17/10118-0, 21/07615-7)