Optical and time-resolved spectroscopic studies on new free-based Corrol molecules

• Grant number: 21/07350-3
• Support Opportunities: Scholarships in Brazil - Scientific Initiation
• Start date: September 01, 2021
• End date: August 31, 2022
• Field of knowledge: Physical Sciences and Mathematics - Physics - Condensed Matter Physics
• Principal Investigator: Leonardo de Boni
• Grantee: Diego França de Oliveira
• Host Institution: Instituto de Física de São Carlos (IFSC). Universidade de São Paulo (USP). São Carlos , SP, Brazil

Abstract

Obtaining the photophysical properties and its time resolved dependence to organic or inorganic compounds using several spectroscopic techniques is extremely important for the understanding of photophysical and photochemical processes, which may be applied in specific research such as photobiological, applied in several areas. With short laser pulses systems, studies with temporal resolutions became more simplified and allowed an understanding of the evolution of photophysical processes in time, such as absorption of excited states, intersystem crossing process, among others. Excited states and their absorptions and temporal evolution, not observed in stationary spectroscopy measurements, could be identified and analyzed in a new point of view, opening new descriptions of the effects induced by light just after the absorption. Within this scope, this project aims to determine the photophysical properties of new free based Corrols molecules. These studies will be carried out in biological solvent media such as water and a 5 percent mixture of Dimethyl Sulfoxide in water. In addition to spectroscopic properties such as absorption and fluorescence, a detailed study of the fluorescence quantum yield and time-resolved fluorescence will be carried out on these media. All these photophysical obtained parameters are essential to determine triplet states formation. Furthermore, depending on the radiative or non-radiative decay rates, it will be possible to determine the application of the compounds for photodynamic therapy or inactivation of microbiological systems, such as fungi and bacteria. (AU)

Scientific publications

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

RODRIGUES, BRUNA M.; VICTORIA, HENRIQUE F. V.; LEITE, GUILHERME; KRAMBROCK, KLAUS; CHAVES, OTAVIO A.; OLIVEIRA, DIEGO F. DE; GARCIA, RAFAEL DE Q.; DE BONI, LEONARDO; COSTA, LUIZ A. S.; IGLESIAS, BERNARDO A.. Photophysical, photobiological, and biomolecule-binding properties of new tri-cationic meso-tri(2-thienyl)corroles with Pt(II) and Pd(II) polypyridyl derivatives. Journal of Inorganic Biochemistry, v. 242, p. 16-pg., 2023-02-11. (20/16036-8, 22/02439-9, 16/20886-1, 18/11283-7, 18/03758-5, 21/07350-3)

PEREIRA, LORENA MARIA BORGES; DE OLIVEIRA, DIEGO FRANCA; TIBURCIO, MARCO ANTONIO; RIBEIRO, GABRIEL H.; MORAES, CARLOS ANDRE FERREIRA; NETO, FLAVIO OLIMPIO SANCHES; CAMARGO, ADEMIR JOAO; DE BONI, LEONARDO; NASCIMENTO, OTACIRO RANGEL; HOMEM, MANOEL G. P.; et al. Exploring the Reversible Equilibrium State between ³CS and ³CSS in a Ru(phen)-Naphthalene Diimide Dyad. Inorganic Chemistry, v. 64, n. 17, p. 10-pg., 2025-04-21. (19/21143-0, 20/16036-8, 21/04675-9, 21/07350-3, 18/11283-7, 23/05917-1, 22/06637-0)

DE OLIVEIRA, DIEGO F.; DO NASCIMENTO, CAROLINA S.; MOURA, NUNO M. M.; FAUSTINO, M. AMPARO F.; MENDONCA, CLEBER R.; DE BONI, LEONARDO. Investigating the excited state dynamics and two-photon absorption of β-functionalized neutral and cationic meso-tetraphenylporphyrins. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, v. 471, p. 9-pg., 2026-02-01. (21/07350-3, 18/11283-7, 23/05917-1)