de Azambuja, Francisco
Daniliuc, Constantin G.
Total Authors: 5
 Univ Munster, Inst Organ Chem, D-48149 Munster - Germany
Total Affiliations: 1
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION;
SEP 1 2014.
Web of Science Citations:
The reactivity and selectivity of 1,3-diynes in transition-metal-catalyzed C-H activation is exploited to quickly assemble diverse polysubstituted bisheterocycles, which are highly important but difficult to access. By using the C-H activation/1,3-diyne strategy, we overcame the challenges of selectivity (chemo-, regio-, and mono-/diannulation) and constructed seven kinds of adjacent bisheterocycles through the formation of four strategic bonds with high efficiency and high selectivity. (AU)