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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Thermoluminescence in Lapis Lazuli crystal: Glow peaks and their connection with F-centers estimated by ESR analysis

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Author(s):
Silva-Carrera, Noemi B. ; Cano, Nilo F. ; Gundu Rao, T. K. ; Ayala-Arenas, Jorge S. ; Watanabe, Shigueo
Total Authors: 5
Document type: Journal article
Source: Journal of Luminescence; v. 188, p. 472-477, AUG 2017.
Web of Science Citations: 3
Abstract

The mineral Lapis Lazuli exhibits three thermoluminescence (TL) peaks approximately at 140, 260 and 370 degrees C. The TL intensity of the three peaks grows with radiation dose and it saturates only beyond 9 kGy. Electron Spin Resonance (ESR) studies have been carried out to identify the defect centers responsible for the thermoluminescence peaks. The ESR spectrum of the as-received natural sample presented the typical six signals due to Mn2+ ion and a large signal around g = 2.030 due to Fe3+ ion. Room temperature ESR spectrum of irradiated Lapis Lazuli shows the formation of a defect center. This center (center I) is identified as an F-center (singly ionized oxygen vacancy) and seems to correlate with 140 and 250 degrees C TL peaks. An additional defect center is observed during thermal annealing experiments and this center (center II - assigned to F+-center) appears to originate from an F-center (oxygen vacancy with two electrons). This F-center, precursor of center II, may be related to the observed high temperature 360 degrees C TL peak in Lapis Lazuli. (AU)

FAPESP's process: 14/03085-0 - Quaternary geochronology of Southeastern and Southern coast of Brazil
Grantee:Shigueo Watanabe
Support Opportunities: Research Projects - Thematic Grants