Thermodynamic and spectroscopic study of binary mixtures of n-butylammonium oleate ionic liquid plus alcohol at T=288.15-308.15 K

Author(s)

Olivieri, Gustavo Vieira ^[1] ; da Cunha, Carolina Sarem ^[1] ; Martins, Lilian dos Santos ^[1] ; Paegle, Pedro Ainis M. ^[1] ; Nuncio, Satya Dias ^[1] ; Morandim-Giannetti, Andreia de Araujo ^[1] ; Torres, Ricardo Belchior ^[1]

Affiliation

^[1] Ctr Univ FEI, Dept Engn Quim, Ave Humberto de Alencar Castelo Branco 3972, BR-09850901 Sao Paulo - Brazil

• Document type: Journal article
• Source: JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY; v. 131, n. 3, p. 2925-2942, MAR 2018.
• Web of Science Citations: 5

Abstract

In this study, experimental data of density and speed of sound have been measured for binary liquid mixtures containing [n-butylammonium oleate (N(4)Ol) ionic liquid + 1-propanol, or + 1-butanol, or + 1-pentanol, or + 1-hexanol], over the entire range of composition at temperatures from T = 288.15-308.15 K and atmospheric pressure. Excess molar volume, , and deviation in isentropic compressibility, Delta kappa, were calculated using the experimental data and were fit to a Redlich-Kister type polynomial. In order to elucidate possible intermolecular interactions between the chemical species present in solution, FT-IR and H-1-NMR spectroscopic analyses were carried out. The results for all systems studied suggest that structural effects and dispersion-type interactions must predominate other possible effects. (AU)

• FAPESP's process: 09/14556-5 - Volumetric, transport, and acoustic properties of binary systems containing ionic liquids: experimental study and modeling
• Grantee: Ricardo Belchior Tôrres
• Support Opportunities: Regular Research Grants