| Full text | |
| Author(s): |
Brito, Gilmar A.
[1, 2]
;
Della-Felice, Franco
[1, 2]
;
Luo, Guoshun
[2]
;
Burns, Alexander S.
[3]
;
Pilli, Ronaldo A.
[1]
;
Rychnovsky, Scott D.
[3]
;
Krische, Michael J.
[2]
Total Authors: 7
|
| Affiliation: | [1] Univ Campinas UNICAMP, Inst Chem, POB 6154, BR-13083970 Campinas, SP - Brazil
[2] Univ Texas Austin, Dept Chem, Austin, TX 78712 - USA
[3] Univ Calif Irvine, Dept Chem, Nat Sci 2 1102, Irvine, CA 92697 - USA
Total Affiliations: 3
|
| Document type: | Journal article |
| Source: | ORGANIC LETTERS; v. 20, n. 13, p. 4144-4147, JUL 6 2018. |
| Web of Science Citations: | 4 |
| Abstract | |
Cyclometalated pi-allyliridium C,O-benzoates modified by (S)-SEGPHOS or (S)-Cl,OMe-BIPHEP catalyze enantioselective 2-propanol-mediated reductive couplings of diverse nonmetallic allyl pronucleophiles with the acetylenic aldehyde TIPSC CCHO. Absolute stereochemistries of the resulting secondary homoallylic-propargylic alcohols were assigned using Rychnovsky's competing enantioselective conversion method. (AU) | |
| FAPESP's process: | 17/00734-5 - Catalytic synthesis of Type II polyketides via Hydrogen-Mediated C-C bond formation |
| Grantee: | Gilmar Araujo Brito Junior |
| Support Opportunities: | Scholarships abroad - Research Internship - Post-doctor |
| FAPESP's process: | 17/18487-4 - Synthesis and structural validation of phosdiecin A |
| Grantee: | Franco Della Felice |
| Support Opportunities: | Scholarships abroad - Research Internship - Doctorate (Direct) |