Univ Calif Irvine, Dept Chem, Nat Sci 2 1102, Irvine, CA 92697 - USA
Total Affiliations: 3
JUL 6 2018.
Web of Science Citations:
Cyclometalated pi-allyliridium C,O-benzoates modified by (S)-SEGPHOS or (S)-Cl,OMe-BIPHEP catalyze enantioselective 2-propanol-mediated reductive couplings of diverse nonmetallic allyl pronucleophiles with the acetylenic aldehyde TIPSC CCHO. Absolute stereochemistries of the resulting secondary homoallylic-propargylic alcohols were assigned using Rychnovsky's competing enantioselective conversion method. (AU)