| Full text | |
| Author(s): |
Reis, Joel S.
[1]
;
Fernandes, Arthur B.
[2]
;
Freitas-Dorr, Barbara C.
[2]
;
Bastos, Erick L.
[2]
;
Stefani, Helio A.
[1]
Total Authors: 5
|
| Affiliation: | [1] Univ Sao Paulo, Fac Ciencias Farmaceut, Dept Farm, Sao Paulo, SP - Brazil
[2] Univ Sao Paulo, Inst Quim, Dept Quim Fundamental, Sao Paulo, SP - Brazil
Total Affiliations: 2
|
| Document type: | Journal article |
| Source: | Tetrahedron; v. 74, n. 48, p. 6866-6872, NOV 29 2018. |
| Web of Science Citations: | 2 |
| Abstract | |
Excited state intramolecular proton transfer (ESIPT) is a widespread phenomenon that has been exploited in several analytical and technological applications. Here we describe the synthesis of two ESIPT-active halogen-substituted naphthol-oxazolines that can be conveniently functionalized to develop tailored sensors, and a bis-oxazoline that showcases the potential of oxazolines to undergo double ESIPT. The photophysical properties of these compounds in solution were investigated using polar aprotic solvents and the results were rationalized using DFT/TD-DFT calculations. (C) 2018 Elsevier Ltd. All rights reserved. (AU) | |
| FAPESP's process: | 14/22136-4 - Use of green solvents and their mixtures for optimizing chemical processes |
| Grantee: | Omar Abou El Seoud |
| Support Opportunities: | Research Projects - Thematic Grants |
| FAPESP's process: | 15/25629-4 - Synthesis of fluorescent nanoparticles using betalains |
| Grantee: | Arthur Bonfá Fernandes |
| Support Opportunities: | Scholarships in Brazil - Doctorate (Direct) |
| FAPESP's process: | 14/10563-5 - Photophysical properties of betalainic metal complexes |
| Grantee: | Barbara Coelho de Freitas Dörr |
| Support Opportunities: | Scholarships in Brazil - Doctorate (Direct) |
| FAPESP's process: | 17/24821-4 - Carbonylative Coupling and Intramolecular Cycloaddition [2 + 2] Reactions Employing D-Glucal |
| Grantee: | Helio Alexandre Stefani |
| Support Opportunities: | Regular Research Grants |
| FAPESP's process: | 16/02392-1 - 2-Aryloxazolines: Synthesis, Biological Activity and Fluorescence |
| Grantee: | Joel Savi dos Reis |
| Support Opportunities: | Scholarships in Brazil - Post-Doctoral |
| FAPESP's process: | 16/21445-9 - Betalains: structure-property relationships |
| Grantee: | Erick Leite Bastos |
| Support Opportunities: | Regular Research Grants |