| Full text | |
| Author(s): |
Meirinho, Anne G.
[1]
;
Pereira, Vinkius F.
[1]
;
Martins, Guilherme M.
[2]
;
Saba, Sumbal
[2]
;
Rafique, Jamal
[3]
;
Braga, Antonio L.
[2]
;
Mendes, Samuel R.
[1]
Total Authors: 7
|
| Affiliation: | [1] Univ Estado Santa Catarina, SINCA, Dept Qulm, BR-89219719 Joinville, SC - Brazil
[2] Univ Fed Santa Catarina, Labselen, Dept Quim, BR-88040900 Florianopolis, SC - Brazil
[3] Univ Fed Mato Grosso do Sul, Inst Quim, BR-79074460 Campo Grande, MS - Brazil
Total Affiliations: 3
|
| Document type: | Journal article |
| Source: | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY; v. 2019, n. 38 AUG 2019. |
| Web of Science Citations: | 1 |
| Abstract | |
Herein, we report an electrochemical oxidative C(sp(2))-H selenylation of activated arenes. The reaction proceeds in an undivided electrochemical cell at Pt-electrodes in the presence of KI as the supporting electrolyte, which could suffer oxidation at the anode. Using this benign, atom-economic protocol, the desired selenylated products were obtained regioselectively in good to excellent yields by using a half molar equiv. of the diselenides. (AU) | |
| FAPESP's process: | 14/50249-8 - Green chemistry: sustainable synthetic methods employing benign solvents, safer reagents, and bio-renewable feedstock |
| Grantee: | Arlene Gonçalves Corrêa |
| Support Opportunities: | Research Grants - Research Centers in Engineering Program |