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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

A base-promoted tandem approach to bicyclic 8-membered ring ketones

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Author(s):
dos Santos, Emerson E. F. [1] ; de Souza, Gabriela F. P. [1] ; Simoni, Deborah A. [1] ; Salles Jr, Airton G.
Total Authors: 4
Affiliation:
[1] Univ Estadual Campinas, Dept Organ Chem, Inst Chem, POB 6154, BR-13084862 Campinas, SP - Brazil
Total Affiliations: 1
Document type: Journal article
Source: ORGANIC & BIOMOLECULAR CHEMISTRY; v. 18, n. 17, p. 3249-3253, MAY 7 2020.
Web of Science Citations: 0
Abstract

A base-promoted tandem route toward unprecedented bicyclic 8-membered ring ketones is reported. Under our approach, the targeted products are delivered in high yields from phenylacetylenes and 1,3-diketones. The method has a good scope and gives access to a complex structure that offers a wealth of opportunities for further functionalization. (AU)

FAPESP's process: 17/18400-6 - Tandem allylic/benzylic oxidation-Michael addition/aldol reaction using TBAI as a single catalyst: An expedient protocol to increase structural complexity.
Grantee:Airton Goncalves Salles Junior
Support Opportunities: Regular Research Grants