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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

The palladium-catalyzed Heck arylation of olefins with arenediazonium salts as a sustainable strategy in organic synthesis

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Author(s):
Oliveira, Caio C. [1] ; Correia, Carlos Roque D. [1]
Total Authors: 2
Affiliation:
[1] Univ Estadual Campinas, Inst Chem, BR-13083970 Sao Paulo - Brazil
Total Affiliations: 1
Document type: Review article
Source: CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY; v. 26, DEC 2020.
Web of Science Citations: 1
Abstract

The palladium-catalyzed Heck arylation of olefins using arenediazonium salts, known as the Heck-Matsuda reaction, constitutes an effective, green, and sustainable way to synthesize functionalized aryl intermediates for organic synthesis. The present review highlights this strategy focusing on some selected examples from our laboratory. The examples include the substrate-directed arylation of olefins - covalent and noncovalent strategies - and their application in the total syntheses of many pharmacologically active compounds, commercial drugs, and/or functional compounds. (AU)

FAPESP's process: 14/25770-6 - New frontiers in cross-coupling reactions promoted by palladium: combining enantioselective catalysis, C-H activations, new materials and in flux reactions aiming at high efficiency and sustainability in synthetic processes
Grantee:Carlos Roque Duarte Correia
Support Opportunities: Research Projects - Thematic Grants
FAPESP's process: 13/07600-3 - CIBFar - Center for Innovation in Biodiversity and Drug Discovery
Grantee:Glaucius Oliva
Support Opportunities: Research Grants - Research, Innovation and Dissemination Centers - RIDC
FAPESP's process: 18/01669-5 - New quiral metal catalysts and their applications in asymmetric catalysis
Grantee:Caio Costa Oliveira
Support Opportunities: Research Grants - Young Investigators Grants