PDMS-urethanesil hybrid multifunctional materials: combining CO2 use and sol-gel processing

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Gunther, Florian ; Lima, Elton F. S. ; Rossi de Aguiar, Kelen M. F. ; Bearzi, Jefferson R. ; Simoes, Mateus B. ; Schneider, Ricardo ; Bini, Rafael A. ; Ribeiro, Sidney J. L. ; Chi Man, Michel Wong ; Rischka, Klaus ; Aguiar, Flavio H. B. ; Pereira, Renata ; Mainardi, Maria do Carmo A. J. ; Rocha, Marina C. ; Malavazi, Iran ; Passeti, Tania A. ; Santos, Marcio L. ; Imasato, Hidetake ; Rodrigues-Filho, Ubirajara Pereira

• Document type: Journal article
• Source: Journal of Sol-Gel Science and Technology; v. 95, n. 3, p. 17-pg., 2020-08-10.

Abstract

CO2 mitigation by cycloaddition to bis-epoxides to obtain bis-cyclocarbonates (CC) paved one way to a new class of polyurethanes (PUs), the non-isocyanate polyurethanes (NIPUs). By using molecules functionalized with alkoxysilyl groups as end chain it is possible to obtain hybrid NIPUs, also called urethanesils, by sol-gel chemistry. Using bis-cyclocarbonate polydimethylsiloxane (CCPDMS) with proper diamines and end-chain amino silanes followed by sol-gel processing leads to versatile hybrid non-isocyanate polydimethylsiloxane urethanes (PDMS-urethanesil). This review reports-besides our recent studies about PDMS-urethanesil materials-the sol-gel chemistry applied to synthesize urethanesil and its applications. While the antimicrobial, photochromic, and anticorrosion properties of urethanesil loaded with phosphotungstic acid as well as the luminescent effect of material loaded with Eu(3+)have already been reported, antimicrobial features of urethanesil loaded with phosphoric acid are our newest findings which we herein report for the first time. The impact of the inorganic acid used on the sol-gel process is highlighted together with the importance of antibiofouling properties. Although the antibiofouling mechanism is still under investigation, the broad spectrum of action of phosphoric acid-loaded urethanesil is worth mentioning, since it has been tested to be efficient against some pathogenic bacteria including a drug resistantStaphylococcus aureusstrain as well as pathogenic fungi and yeast. Due to the simple, straightforward, and highly reproducible synthesis as well as the opportunity to obtain versatile materials with tuneable mechanical and physical properties, this new class of hybrid materials promises to be applicable in different industrial fields. [GRAPHICS] (AU)

• FAPESP's process: 11/08120-0 - Nanostructured films: on the influence of the architecture on Photoactivity properties of films with phosphotungstate and nanoparticles
• Grantee: Ubirajara Pereira Rodrigues Filho
• Support Opportunities: Regular Research Grants
• FAPESP's process: 18/19785-1 - CO2 as a raw material for hybrid multi-functional materials: improving the sustainability of industrial processes
• Grantee: Ubirajara Pereira Rodrigues Filho
• Support Opportunities: Research Program on Global Climate Change - Regular Grants
• FAPESP's process: 13/05279-3 - Poly(dimethylsiloxane) based segmented urethanes biomimetic adhesives Based on CO2 fixation
• Grantee: Kelen Menezes Flores Rossi de Aguiar
• Support Opportunities: Scholarships abroad - Research Internship - Doctorate
• FAPESP's process: 11/06019-0 - CO2 uptake and synthesis of polyuretanes-polysilicone co-polymers as additives incorporated in ormosils: use on bioactive and ion conducting films
• Grantee: Kelen Menezes Flores Rossi de Aguiar
• Support Opportunities: Scholarships in Brazil - Doctorate
• FAPESP's process: 18/15670-5 - Novel Semiconducting Materials based on PDMS and DPP for Flexible and Stretchable Electronics: Fabrication, Analysis and Applications in Organic Devices
• Grantee: Florian Steffen Günther
• Support Opportunities: Scholarships in Brazil - Post-Doctoral