Metal-glycerolates and their derivatives as electrode materials: A review on recent developments, challenges, and future perspectives

Author(s)

Goncalves, Josue M. ; Hennemann, Artur Luis ; Ruiz-Montoya, Jose G. ; Martins, Paulo R. ; Araki, Koiti ; Angnes, Lucio ; Shahbazian-Yassar, Reza

• Document type: Journal article
• Source: Coordination Chemistry Reviews; v. 477, p. 29-pg., 2023-02-15.

Abstract

The need for alternative forms of energy conversion and storage requires preparation of novel nanostruc-tured material architectures. The emerging metal-glycerolates and their derivatives are promising classes of materials that can be prepared in various morphologies including porous, hollow, or yolk-shell struc-tures. Such materials encompass a vast compositional space spanning from metal oxides to metal hydroxides, metal sulfides, and metal phosphides. This review addresses the synthesis of micro-and nanostructures derived from metal-glycerolate, using different preparation processes, as well as the applications of these materials, especially for the preparation of supercapacitors and batteries electrodes, as well as electrocatalysts for water splitting. In fact, the utilization of metal-glycerolates and their derivatives as electrode materials is a very recent theme attested by the fact that about 85% of the refer-ences reported in this review are published in the 2018-2022 period. In addition, the developments, chal-lenges, and future perspectives as well as the future directions of these promising materials are discussed.(c) 2022 Elsevier B.V. All rights reserved. (AU)

• FAPESP's process: 18/16896-7 - Development of amperometric and impedimetric sensors based on double hydroxides of nickel and vanadium (alpha-NixV1-x(OH)2) and their nanocomposites with expandable graphite/graphene
• Grantee: Josué Martins Gonçalves
• Support Opportunities: Scholarships in Brazil - Post-Doctoral
• FAPESP's process: 18/21489-1 - Supramolecular nanotechnology: design, materials and devices
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• FAPESP's process: 17/13137-5 - Formation and properties of hemiesters of carbonic acid in aqueous medium
• Grantee: Claudimir Lucio Do Lago
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• FAPESP's process: 13/24725-4 - Supramolecular chemistry and nanotechnology
• Grantee: Henrique Eisi Toma
• Support Opportunities: Research Projects - Thematic Grants
• FAPESP's process: 20/06176-7 - Studying the layered hydroxide electrode materials with in situ transmission electron microscopy
• Grantee: Josué Martins Gonçalves
• Support Opportunities: Scholarships abroad - Research Internship - Post-doctor