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Supramolecular nanotechnology: design, materials and devices

Abstract

Nanotechnology based on a supramolecular approach is the subject of this research proposal. New supramolecular structures encompassing metal-polypyridines, tetrapyridylporphyrins, tetraaza-porphyrazines and triangular Ru3O clusters are being assembled, aiming the generation of high performance electro/photo catalysts, sensors and photoelectrochemical cells. Nanoparticles bearing a supramolecular design are being elaborated from plasmonic (Ag, Au), semiconductor (TiO2), superparamagnetic (Fe3O4 and g-Fe2O3) and quantum dots (CdTe, C*) cores, which are stabilized with suitable protecting coatings, such as of SiO2 and polymers. Then, they are modified with specific functional agents, aiming biological and medical applications, and the development of new, green, biotechnological and hydrometallurgical processes. New supramolecular dye TiO2 cells incorporating a vectorial design are being developed. Superparamagnetic and plasmonic gold nanoparticles are being attached to screen printed gold electrodes for performing magnetically confined electroanalysis and in situ SERS spectroelectrochemistry. Chelating superparamagnetic nanoparticles are being used for the capture and processing of metal ions, based on magnetic nanohydrometallurgy, including the separation of rare earth elements. Enzymes immobilized onto superparamagnetic nanoparticles are being applied in synthetic chemistry and enantiomeric resolution of chemical species. Finally, multifunctional engineered nanoparticles are being developed for a wide variety of medical applications, including theranostic and MRI contrasting agents. The proposal encompasses two research groups with 35 participants, and involves strong national and international collaboration with many different institutions and industries. (AU)

Articles published in Pesquisa para Inovação FAPESP about research grant:
Molecule derived from colorant inactivates SARS-CoV-2 and can be used in oral hygiene products 
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Scientific publications (36)
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
KAID, FELIPE F.; SILVEIRA JUNIOR, ALCEU T.; TOMA, HENRIQUE E.. Langmuir Isotherms for Functionalized Superparamagnetic Nanoparticles with Cobalt(II) Ions Based on Zeta Potentials. ACS APPLIED NANO MATERIALS, v. 3, n. 1, p. 452-458, . (18/21489-1)
ROSSINI, PAMELA DE O.; LAZA, ANABEL; AZEREDO, NATHALIA F. B.; GONCALVES, JOSUE M.; FELIX, FABIANA S.; ARAKI, KOITI; ANGNES, LUCIO. Ni-based double hydroxides as electrocatalysts in chemical sensors: A review. TRAC-TRENDS IN ANALYTICAL CHEMISTRY, v. 126, . (14/50867-3, 18/16896-7, 18/21489-1, 17/13137-5)
AZEREDO, NATHALIA F. B.; GONCALVES, JOSUE M.; ROSSINI, PAMELA O.; ARAKI, KOITI; WANG, JOSEPH; ANGNES, LUCIO. Uric acid electrochemical sensing in biofluids based on Ni/Zn hydroxide nanocatalyst. Microchimica Acta, v. 187, n. 7, . (14/50867-3, 17/13137-5, 18/21489-1, 18/16896-7)
GONCALVES, JOSUE M.; MARTINS, PAULO R.; ANGNES, LUCIO; ARAKI, KOITI. Recent advances in ternary layered double hydroxide electrocatalysts for the oxygen evolution reaction. NEW JOURNAL OF CHEMISTRY, v. 44, n. 24, p. 9981-9997, . (18/16896-7, 13/24725-4, 18/21489-1)
DE MELO, FERNANDO M.; ALMEIDA, SABRINA N.; TOMA, HENRIQUE E.. Magnetic Nanohydrometallurgy Applied to Lanthanide Separation. MINERALS, v. 10, n. 6, . (18/21489-1)
DE MELO, FERNANDO MENEGATTI; MATTIONI, V, JOAO; DIAS, FERNANDO; FU, YING; TOMA, HENRIQUE E.. Solvophobic-controlled synthesis of smart magneto-fluorescent nanostructures for real-time inspection of metallic fractures. NANOSCALE ADVANCES, v. 3, n. 12, p. 3593-3604, . (19/14771-5, 18/21489-1)
SOARES, R. S. B.; SOUZA, L. R. R.; BERTOLUCCI, M. M.; OLIVEIRA, A. DE; DEMETS, G. J. F.; ARAKI, K.. Critical Parameters for Green Glycoluril Synthesis. RUSSIAN JOURNAL OF GENERAL CHEMISTRY, v. 91, n. 4, p. 739-742, . (18/21489-1)
GONCALVES, JOSUE M.; MARTINS, PAULO R.; ARAKI, KOITI; ANGNES, LUCIO. Recent progress in water splitting and hybrid supercapacitors based on nickel-vanadium layered double hydroxides. JOURNAL OF ENERGY CHEMISTRY, v. 57, p. 496-515, . (18/16896-7, 13/24725-4, 18/21489-1)
MAMIAN-LOPEZ, MONICA BENICIA; MIGUEL, RODRIGO BERNARDI; ARAKI, KOITI; TEMPERINI, MARCIA L. A.; DA COSTA FERREIRA, ANA MARIA. Multivariate probing of antitumor metal-based complexes damage on living cells through Raman imaging. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, v. 244, . (14/07841-3, 16/21070-5, 12/13119-3, 18/21489-1, 13/07937-8)
ROMANO, MARIANA; UCHIYAMA, MAYARA K.; CARDOSO, ROBERTA M.; TOMA, SERGIO H.; BAPTISTA, MAURICIO S.; ARAKI, KOITI. Nitric oxide inhibition of lipopolysaccharide-stimulated RAW 247.6 cells by ibuprofen-conjugated iron oxide nanoparticles. Nanomedicine, v. 15, n. 25, p. 2475-2492, . (18/21489-1, 13/07937-8)
GONCALVES, JOSUE M.; DA SILVA, MATHEUS IRENO; ANGNES, LUCIO; ARAKI, KOITI. Vanadium-containing electro and photocatalysts for the oxygen evolution reaction: a review. JOURNAL OF MATERIALS CHEMISTRY A, v. 8, n. 5, p. 2171-2206, . (18/16896-7, 18/21489-1)
ANA P. MANGONI; BRUNO B. N. S. BRANDÃO; JORGE S. SHINOHARA; ALCEU T. SILVEIRA; MARCELO NAKAMURA; HENRIQUE E. TOMA. RAMAN STUDIES OF BIS(PHENYLTERPYRAZINE)IRON(II) AND SUPRAMOLECULAR SPECIES WITH PENTACYANIDOFERRATE(II) IONS. Química Nova, v. 42, n. 9, p. 1020-1028, . (18/21489-1)
GONCALVES, JOSUE M.; KUMAR, ABHISHEK; DA SILVA, MATHEUS I.; TOMA, HENRIQUE E.; MARTINS, PAULO R.; ARAKI, KOITI; BERTOTTI, MAURO; ANGNES, LUCIO. Nanoporous Gold-Based Materials for Electrochemical Energy Storage and Conversion. ENERGY TECHNOLOGY, v. 9, n. 5, . (18/16896-7, 17/13137-5, 18/21489-1)
VIVIANE VIECELLI; OTÁVIO A. CHAVES; KOITI ARAKI; PAULO R. MARTINS; BERNARDO A. IGLESIAS. Synthesis, Characterization, Spectroelectrochemical, Photophysical and HSA-Binding Properties of Novel and Versatile meso-Tetra(4-pyridylvinylphenyl)porphyrins Coordinated to Ruthenium(II)-Polypyridyl Derivatives. Journal of the Brazilian Chemical Society, v. 31, n. 11, p. 2282-2298, . (18/21489-1)
DA SILVA SANTOS, PAULO SERGIO; DA FONSECA ORCINA, BERNARDO; MACHADO, RAFAEL RAHAL GUARAGNA; VILHENA, FABIANO VIEIRA; DA COSTA ALVES, LUCAS MARQUES; ZANGRANDO, MARIANA SCHUTZER RAGGHIANTI; DE OLIVEIRA, RODRIGO CARDOSO; SOARES, MARIANA QUIRINO SILVEIRA; SIMAO, ANDREA NAME COLADO; PIETRO, EMILENE CRISTINE IZU NAKAMURA; et al. Beneficial effects of a mouthwash containing an antiviral phthalocyanine derivative on the length of hospital stay for COVID-19: randomised trial. SCIENTIFIC REPORTS, v. 11, n. 1, . (18/21489-1)
GONCALVES, JOSUE M.; DA SILVA, MATHEUS I.; HASHEMINEJAD, MEISAM; TOMA, HENRIQUE E.; ARAKI, KOITI; MARTINS, PAULO R.; ANGNES, LUCIO. Recent Progress in Core@Shell Sulfide Electrode Materials for Advanced Supercapacitor Devices. BATTERIES & SUPERCAPS, v. 4, n. 9, p. 1397-1427, . (18/21489-1, 18/16896-7, 14/50867-3, 13/24725-4, 17/13137-5)
SANTOS, JONNATAN J.; TOMA, SERGIO H.; MONEZI, NATALIA M.; ANDO, ROMULO A.; CORIO, PAOLA; ARAKI, KOITI. Selecting the Mechanism of Surface-Enhanced Raman Scattering Effect using Shell Isolated Nanoparticles and an Oxo-Triruthenium Acetate Cluster Complex. Inorganic Chemistry, v. 58, n. 15, p. 10399-10407, . (16/21070-5, 19/08641-1, 18/21489-1)
AGUIRRE-ARAQUE, JUAN S.; GUIMARAES, ROBSON R.; TOMA, HENRIQUE E.. Chemistry of ternary monocarboxyterpyridine-bipyridine-trimercaptotriazine ruthenium complexes and application in dye sensitized solar cells. Polyhedron, v. 182, . (18/21489-1)
GONCALVES, JOSUE M.; MATIAS, TIAGO A.; ANGNES, LUCIO; MARTINS, PAULO R.; ARAKI, KOITI. Review-Tetraruthenated Porphyrins and Composites as Catalysts and Sensor Materials: A Short Review. ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY, v. 9, n. 6, . (13/24725-4, 18/16896-7, 17/13137-5, 18/21489-1, 17/50129-0, 14/50867-3)
DEDA, DAIANA K.; CARDOSO, ROBERTA M.; KAWASSAKI, RODRIGO K.; DE OLIVEIRA, ANDRE R.; TOMA, SERGIO H.; BAPTISTA, MAURICIO S.; ARAKI, KOITI. Cytotoxicity of Methotrexate Conjugated to Glycerol Phosphate Modified Superparamagnetic Iron Oxide Nanoparticles. Journal of Nanoscience and Nanotechnology, v. 21, n. 3, p. 1451-1461, . (18/21489-1, 19/02151-2)
HENRIQUE EISI TOMA; DANIEL OLIVEIRA; FERNANDO M. DE MELO. Magnetic alignment of rhodamine/magnetite dual-labeled microtubules probed with inverted fluorescence microscopy. Anais da Academia Brasileira de Ciências, v. 94, n. 3, . (18/21489-1, 15/01271-3)
KUMAR, ABHISHEK; FURTADO, VINICIUS L.; GONCALVES, JOSUE M.; BANNITZ-FERNANDES, RENATA; NETTO, LUIS EDUARDO S.; ARAKI, KOITI; BERTOTTI, MAURO. Amperometric microsensor based on nanoporous gold for ascorbic acid detection in highly acidic biological extracts. Analytica Chimica Acta, v. 1095, p. 61-70, . (18/08782-1, 18/21489-1, 18/09027-2)
STRUNCOVA, MARINA; TOMA, SERGIO HIROSHI; ARAKI, KOITI; BRESCIANI, EDUARDO; RODRIGUES, FLAVIA PIRES; MEDEIROS, IGOR STUDART; DUTRA-CORREA, MARISTELA. Silver nanoparticles added to a commercial adhesive primer: Colour change and resin colour stability with ageing. INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES, v. 102, . (18/21489-1)
JONNATAN J. SANTOS; SERGIO H. TOMA; REBECA E. YATSUZUKA; KOITI ARAKI. Gold Nanoparticle/Tetrapyridylporphyrin Hybrid Material: Spectroscopic and Electrocatalytic Properties and Sensor Application. Journal of the Brazilian Chemical Society, v. 31, n. 11, p. 2274-2281, . (18/21489-1)
HELTON P. NOGUEIRA; SERGIO H. TOMA; ALCEU T. SILVEIRA JR.; KOITI ARAKI. Zeolite-SPION Nanocomposite for Ammonium and Heavy Metals Removal from Wastewater. Journal of the Brazilian Chemical Society, v. 31, n. 11, p. 2342-2350, . (18/21489-1)
ROSERO, WILMMER A. A.; GUIMARAES, ROBSON R.; MATIAS, TIAGO A.; ARAKI, KOITI. Effect of Push-Pull Ruthenium Complex Adsorption Conformation on the Performance of Dye Sensitized Solar Cells. Journal of the Brazilian Chemical Society, v. 31, n. 11, p. 2250-2264, . (18/21489-1)
UCHIYAMA, MAYARA K.; HEBEDA, CRISTINA B.; SANDRI, SILVANA; PAULA-SILVA, MARINA DE; ROMANO, MARIANA; CARDOSO, ROBERTA M.; TOMA, SERGIO H.; ARAKI, KOITI; FARSKY, SANDRA H. P.. In vivo evaluation of toxicity and anti-inflammatory activity of iron oxide nanoparticles conjugated with ibuprofen. Nanomedicine, v. 16, n. 9, . (18/21489-1, 14/07328-4)
KUMAR, ABHISHEK; GONCALVES, JOSUE M.; LIMA, ALAN R.; MATIAS, TIAGO A.; NAKAMURA, MARCELO; BERNARDES, JULIANA S.; ARAKI, KOITI; BERTOTTI, MAURO. Efficient and methanol resistant noble metal free electrocatalyst for tetraelectronic oxygen reduction reaction. Electrochimica Acta, v. 326, . (18/08782-1, 18/21489-1)
GONCALVES, JOSUE M.; DA SILVA, MATHEUS L.; TOMA, HENRIQUE E.; ANGNES, LUCIO; MARTINS, PAULO R.; ARAKI, KOITI. Trimetallic oxides/hydroxides as hybrid supercapacitor electrode materials: a review. JOURNAL OF MATERIALS CHEMISTRY A, v. 8, n. 21, p. 10534-10570, . (18/16896-7, 18/21489-1, 17/13137-5)
PEFFI FERREIRA, LUIS FERNANDO; MAZZI DE OLIVEIRA, THAYNA; TOMA, SERGIO HIROSHI; TOYAMA, MARCOS MAKOTO; ARAKI, KOITI; AVANZI, LUIS HUMBERTO. Superparamagnetic iron oxide nanoparticles (SPIONs) conjugated with lipase Candida antarctica A for biodiesel synthesis. RSC ADVANCES, v. 10, n. 63, p. 38490-38496, . (18/21489-1)
DEDA, DAIANA K.; IGLESIAS, BERNARDO A.; ALVES, EDUARDO; ARAKI, KOITI; GARCIA, CELIA R. S.. Porphyrin Derivative Nanoformulations for Therapy and Antiparasitic Agents. Molecules, v. 25, n. 9, . (17/08684-7, 18/07177-7, 18/21489-1)
QUARTAROLLI, LUCAS F.; SILVEIRA, ALCEU T.; TOMA, HENRIQUE E.. Overcoming lithium analysis difficulties with a simple colorimetric/spectrophotometric method. ANALYTICAL METHODS, v. 13, n. 32, p. 3627-3631, . (18/21489-1)
HENRIQUE E. TOMA. GALILEO’S PENDULUM AS A MAGNETIC BALANCE FOR STUDYING CHEMICAL MAGNETISM AT HOME. Química Nova, v. 44, n. 1, p. 112-117, . (18/21489-1)
DA SILVA, I, MATHEUS; MACHADO, ITALO R.; TOMA, HENRIQUE E.; ARAKI, KOITI; ANGNES, LUCIO; GONCALVES, JOSUE M.. Recent progress in water-splitting and supercapacitor electrode materials based on MOF-derived sulfides. JOURNAL OF MATERIALS CHEMISTRY A, v. 10, n. 2, . (13/24725-4, 18/21489-1, 18/16896-7)
TOMA, HENRIQUE EISI. Microscale Educational Kits for Learning Chemistry at Home. Journal of Chemical Education, v. 98, n. 12, p. 3841-3851, . (18/21489-1)
BRANDAO, BRUNO B. N. S.; SIHN, LUCA M.; DE MELO, FERNANDO M.; TOMA, HENRIQUE E.. A luminescent boron difluoride derivative of the YELLOW 101 dye. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, v. 261, . (18/21489-1)

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