3-arylthioimidazo[1,2-a]pyridine derivatives: A theoretical and experimental study of its photophysical properties

Author(s)

Cocca, Leandro H. Zucolotto ; Pelosi, Andre G. ; Valverde, Joao V. P. ; le Bescont, Julie ; Breton-Patient, Chloe ; Piguel, Sandrine ; Mendonca, Cleber R. ; De Boni, Leonardo

• Document type: Journal article
• Source: JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY; v. 440, p. 10-pg., 2023-06-01.

Abstract

The optical properties of imidazo[1,2-a]pyridines possessing various arylthiol substituents at position 3 are described for the first time. Several optical spectroscopy studies were performed to investigate the influence of the electronic effects of the substituents on the thioaryl group and the influence of the sulfur atom as a linker. The compounds exhibited two absorption bands, which are related to the & pi;& RARR;& pi;* transitions, and wide Stokes shift of ca. 100 nm were obtained owing to a substantial electronic modification in the excited state. The fluorescence quantum yield increased by 90% when replacing the trifluoromethyl peripheral group with fluorine. Moreover, it was observed that permanent dipole moment values increase as strength electron-donating or electron-withdrawing substituents groups, which is associate to Hammett constant. In conclusion, this experimental and theoretical study revealed a possible way in view of to optimize the 3-arylthioimidazo[1,2-a]pyridine de-rivatives optical properties through peripherals groups substitution. (AU)

• FAPESP's process: 11/12399-0 - Femtosecond pulses applied to nonlinear optics: spectroscopy, pulse shaping and microfabrication
• Grantee: Cleber Renato Mendonça
• Support Opportunities: Research Projects - Thematic Grants
• FAPESP's process: 15/20032-0 - Study on Nonlinear and Charge Transport Properties of Multi-branched Molecules via Quantum Chemical Methods.
• Grantee: Daniel Luiz da Silva
• Support Opportunities: Regular Research Grants
• FAPESP's process: 16/20886-1 - Ultrafast nonlinear optical spectroscopy: Transient Absorption and optical Kerr Gate with polarization control
• Grantee: Leonardo de Boni
• Support Opportunities: Regular Research Grants
• FAPESP's process: 18/11283-7 - Nonlinear photonics: spectroscopy and advanced processing of materials
• Grantee: Cleber Renato Mendonça
• Support Opportunities: Research Projects - Thematic Grants