Electrochemical sensor based on epoxy-functionalized BEA nanozeolite and graphene oxide modified glassy carbon electrode for bisphenol E determination

Author(s)

Miller, Alex H. ; Nguyen, Huong Thi-Thanh ; Nery, Jose G. ; Fielding, Alistair J.

• Document type: Journal article
• Source: Journal of Applied Electrochemistry; v. 53, n. 8, p. 11-pg., 2023-03-18.

Abstract

An epoxy-functionalized beta type nanozeolite (BEA)/graphene oxide nanocomposite modified glassy carbon electrode (GCE/BEA/APTMS/GA/GO/NF) has been created for the differential pulse voltammetric determination of bisphenol E (BPE). The modified electrode presented an enhanced current response in comparison with bare GCE. A linear dependence of anodic peak current (I-p) and scan rate (nu) was observed, which showed that the electrochemical process was adsorption-controlled. Differential pulse voltammetry (DPV) was employed and optimized for the sensitive determination of BPE. Under the optimized conditions, the anodic peak current was linearly proportional to BPE concentration in the range between 0.07 and 4.81 mu M, with a correlation coefficient of 0.995 and limit of detection 0.056 mu M (S/N = 3). The electrode showed good repeatability and storage stability, and a low response to interfering compounds. Comparison was made to the determination of bisphenol A. To confirm the electrode analytical performance, recovery tests were performed, and deviations lower than 10% were found. The BEA zeolite-GO nanocomposite proved to be a promising sensing platform for bisphenol determination. [GRAPHICS] . (AU)

• FAPESP's process: 16/24303-0 - Synthesis and characterization of new biocatalysts formed by nanozeolite and laccase enzymes complexes: their applications in oxidation reactions of glycerol to tartronic acid and mesoxalic acid compounds
• Grantee: Alex Henrique Miller
• Support Opportunities: Scholarships in Brazil - Doctorate
• FAPESP's process: 18/21483-3 - Laccase/TEMPO-mediated glycerol oxidation spectroscopic and electrochemical assessment
• Grantee: Alex Henrique Miller
• Support Opportunities: Scholarships abroad - Research Internship - Doctorate