Properties of Thin Film Composites of rGO-SnO₂ and Modeling of Ultraviolet Laser-Induced Conductivity Decay

Author(s)

de Almeida, Andre Luis ; Fonseca, Lucas Prado ; de Oliveira, Natalia Carli ; Martins, Lucas Michelao ; Bueno, Cristina de Freitas ; Scalvi, Luis Vicente de Andrade

• Document type: Journal article
• Source: CHEMISTRYSELECT; v. 9, n. 39, p. 11-pg., 2024-10-01.

Abstract

Reduced graphene oxide (rGO) and tin dioxide (SnO2) form composites in a wide range of SnO2/rGO proportions, which are deposited as thin films on borosilicate glass and silica substrates. The rGO proportion affects the SnO2 optical properties and the sample surface, as observed by optical transmittance and confocal and scanning electron microscopies images, mainly for high proportion of rGO. For low proportion, the presence of small surface islands may contribute to optical confinement. The evaluated bandgap is basically from the SnO2 matrix unless the presence of rGO affects the optical absorption edge. Monochromatic ultraviolet light from a He-Cd laser (325 nm) irradiating on the composite film increases the conductivity, giving rise to the phenomenon of persistent photoconductivity (PPC), even very close to room temperature. Modeling by considering mainly the SnO2/rGO interface barrier for electron transport, yield an interface energy barrier of 250 meV. The strong response to ultraviolet light and the phenomenon of PPC indicates potential application in amplifiers, which could be adjusted by doping with rare-earth ions, such as Er3+ in the SnO2 matrix. (AU)

• FAPESP's process: 22/12998-5 - Investigation of the oxide semiconductor TiO2, as thin films, and combination with quinoline derivatives, aiming to technological applications
• Grantee: Natalia Carli de Oliveira
• Support Opportunities: Scholarships in Brazil - Scientific Initiation
• FAPESP's process: 22/08483-0 - Coupling of the oxide semiconductor SnO2 as thin film with quinoline derivatives for optoelectronic applications
• Grantee: Lucas Prado Fonseca
• Support Opportunities: Scholarships in Brazil - Master