Ru(II)-catalyzed ortho C-H Arylation of Heterocyclic Biaryls

Full text
Author(s):	Pinheiro, Erick M. C. ; Couto, Daniel P. ; Oliveira, Caio C. Total Authors: 3
Document type:	Journal article
Source:	ASIAN JOURNAL OF ORGANIC CHEMISTRY; v. N/A, p. 5-pg., 2024-11-23.
Abstract
Ru(II)-Pheox complexes are known catalysts for carbene insertion reactions. Herein we teach them a new trick: how to perform ortho C-H arylation processes! Our operationally simple protocol tolerates structurally diverse directing groups and both aryl iodides and diaryliodonium salts as transfer groups. (AU)

FAPESP's process:	20/12435-5 - Synthesis of new enantioenriched half-sandwich ligands and its applications to enantioselective ruthenium-catalyzed C-H functionalization reactions
Grantee:	Erick Martins de Carvalho Pinheiro
Support Opportunities:	Scholarships in Brazil - Doctorate (Direct)


FAPESP's process:	23/11514-7 - Synthesis of Ru(II)-oxazoline complexes and application in C-H functionalization.
Grantee:	Erick Martins de Carvalho Pinheiro
Support Opportunities:	Scholarships in Brazil - Doctorate (Direct)


FAPESP's process:	18/01669-5 - New quiral metal catalysts and their applications in asymmetric catalysis
Grantee:	Caio Costa Oliveira
Support Opportunities:	Research Grants - Young Investigators Grants