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Lipidic biomass as a renewable chemical building block for polymeric materials

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Author(s):
Alarcon, Rafael Turra ; dos Santos, Gabriel Iago ; Gaglieri, Caroline ; de Moura, Aniele ; Cavalheiro, Eder Tadeu Gomes ; Bannach, Gilbert
Total Authors: 6
Document type: Journal article
Source: CHEMICAL COMMUNICATIONS; v. N/A, p. 16-pg., 2024-11-11.
Abstract

Polymers are intrinsically connected to modern society and are found and used in a variety of technologies. Although polymers are valuable, concerns about synthetic polymers derived from non-renewable sources have emerged. Therefore, there is a need to develop new polymeric materials from renewable sources, especially those that are cost-effective, non-toxic, widely available, not derived from depleting sources and are designed to be biodegradable after disposal. In this regard, a perfect class of renewable resources are the lipids (not soluble in water), among which, we can find useful compounds such as triacylglycerols/triglycerides (vegetable oil), terpenes/terpenoids (essential oils), and abietic acid (rosin resin). These are liable to modification to new monomers that can be used in adhesives, 3D-printing, self-healing and so on. However, these materials still suffer from some limitations when compared to non-renewable polymers. Therefore, in this feature article, we will present a description/review of these renewable sources together with related polymeric materials and their mechanical/chemical/physical properties and applications. (AU)

FAPESP's process: 22/15211-6 - Preparation and Application of Composite Electrodes Based on Graphite and Polymers: miniaturization, screen printed electrodes and flexible sensors
Grantee:Éder Tadeu Gomes Cavalheiro
Support Opportunities: Regular Research Grants
FAPESP's process: 23/14645-5 - Development of new renewable polymers from limonene and curcumin following the green chemistry principles
Grantee:Aniele de Moura
Support Opportunities: Scholarships in Brazil - Post-Doctoral
FAPESP's process: 24/00779-2 - Application of rosin acids and their derivatives to produce polymers by additive manufacture and in cyclic carbonates syntheses
Grantee:Caroline Gaglieri
Support Opportunities: Scholarships in Brazil - Post-Doctoral
FAPESP's process: 22/03489-0 - SYNTHESIS AND CHARACTERIZATION OF NEW BIOPOLYMER MATERIALS OBTAINED FROM MALEIC ANHYDRIDE AND GLYCEROL USING POLYAMINES AND POLYTHIOLS AS CROSS-LINKING
Grantee:Gabriel Iago dos Santos
Support Opportunities: Scholarships in Brazil - Scientific Initiation
FAPESP's process: 21/14879-0 - New synthetic method of poly-hidroxyurethanes from triacylglycerol using catalysts or triacylmelamine to inhibition side reactions
Grantee:Rafael Turra Alarcon
Support Opportunities: Scholarships in Brazil - Post-Doctoral