A greenness evaluation of deep eutectic solvents-based conventional extraction methods for elemental determination by spectrometry techniques

Author(s)

Costa, Floriatan Santos ; Moreira, Luana Santos ; da Silva, Erik Galva Paranhos ; Gonzalez, Mario Henrique ; Amaral, Clarice D. B.

• Document type: Journal article
• Source: TRAC-TRENDS IN ANALYTICAL CHEMISTRY; v. 174, p. 9-pg., 2024-04-13.

Abstract

Sample preparation for elemental determination remains challenging, complex, and environmentally problematic. Recent advancements have been achieved by utilizing deep eutectic solvents (DES) in conventional extraction methods applied to many matrices and this article provides an evaluation of these applications. The DES -based methods were evaluated for their greenness using the analytical greenness metric (AGREE) and the analytical greenness metric for sample preparation (AGREEprep). The methods comparisons were conducted through exploratory data analysis using a self -organizing map (SOM) to relate the parameters of the methods, characteristics and relations between variables, and associate the data with the AGREE and AGREEprep scores. This review enhances understanding of the implications linked to incorporating DES into sample preparation methods, offering insights for enhancing sustainability and performance in future applications. (AU)

• FAPESP's process: 21/14759-5 - Sustainable solvents and extraction techniques in green analytical chemistry for determination of emerging and inorganic contaminants in environmental samples
• Grantee: Mario Henrique Gonzalez
• Support Opportunities: Regular Research Grants
• FAPESP's process: 19/22113-8 - Natural Deep Eutectic Solvents: synthesis, characterization, and application for the determination of As, Cd, Cr, Hg, Se, and V in environmental samples using ICP-MS
• Grantee: Mario Henrique Gonzalez
• Support Opportunities: Regular Research Grants