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Thermoplastic polyurethanes: synthesis, fabrication techniques, blends, composites, and applications

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Author(s):
Backes, Eduardo Henrique ; Harb, Samarah Vargas ; Pinto, Leonardo Alves ; de Moura, Nayara Koba ; de Melo Morgado, Guilherme Ferreira ; Marini, Juliano ; Passador, Fabio Roberto ; Pessan, Luiz Antonio
Total Authors: 8
Document type: Journal article
Source: Journal of Materials Science; v. 59, n. 4, p. 30-pg., 2024-01-18.
Abstract

Thermoplastic polyurethanes (TPUs) have attracted increasing attention from the scientific and industrial communities due to their rich chemistry and wide fabrication techniques, which open up a vast field of application. Incorporating other polymers or fillers in TPU composition further expands TPU applicability. TPU blends and composites have been explored in medicine, agriculture, textiles, electronics, aeronautics, food packing, sensors, and automobiles. Soft and hard segments of different compositions have been combined to produce TPUs with specific properties, such as soft touch, elasticity, transparency, impact strength, chemical resistance, and elastic memory. Although petroleum-based precursors are still the most applied, green sources of diisocyanate, polyol, and chain extenders have been increasingly exploited. This review first addresses the fundamental chemistry, synthesis, fabrication techniques, and structure of TPUs and further compiles works on TPU blends and composites. (AU)

FAPESP's process: 19/27415-2 - Bioactive scaffolds with surface modification by plasma
Grantee:Luiz Antonio Pessan
Support Opportunities: Regular Research Grants
FAPESP's process: 17/11366-7 - Development of bio-inspired PLA/bioglass scaffolds via 3D printed
Grantee:Eduardo Henrique Backes
Support Opportunities: Scholarships in Brazil - Doctorate
FAPESP's process: 18/26060-3 - Bioactive and bactericidal scaffolds for bone regeneration via 3D printing
Grantee:Samarah Vargas Harb
Support Opportunities: Scholarships in Brazil - Post-Doctoral
FAPESP's process: 20/12501-8 - Development of antistatic and biodegradable packages based on hybrid polyester composites with the addition of glassy carbon and graphene nanoplates
Grantee:Fabio Roberto Passador
Support Opportunities: Regular Research Grants