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Photoelectrochemical Performance of Brookite Titanium Dioxide Electrodeposited on Graphene Foam for Portable Biosensors

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Author(s):
Bott-Neto, Jose L. ; Martins, Thiago S. ; Pimentel, Gabriel J. C. ; Oliveira, Osvaldo N. ; Marken, Frank
Total Authors: 5
Document type: Journal article
Source: ACS OMEGA; v. 9, n. 52, p. 7-pg., 2024-12-16.
Abstract

We discuss the photoelectroanalytical performance of a brookite-phase titanium dioxide (TiO2) platform electrodeposited onto graphene foam (GF) at low temperatures. The scalable electrosynthesis process eliminates the need for thermal annealing, which is impractical for carbon-based electrodes. Films resulting from a 10 min electrodeposition (TiO2-10/GF) exhibit enhanced photocurrents, reaching 170 mu A cm-2 GEO-twice the value for TiO2 films on traditional screen-printed carbon electrodes (82 mu A cm-2 GEO). The increased photocurrent density makes TiO2-10/GF ideal for on-site photoelectrochemical biosensors as it allows for the use of compact systems with low-power LEDs. (AU)

FAPESP's process: 22/03758-0 - Integrated dual electrochemical device for multiplexed detection of biomarkers
Grantee:Thiago Serafim Martins
Support Opportunities: Scholarships in Brazil - Post-Doctoral
FAPESP's process: 22/00243-0 - Developing new components and processes in visible light activated biosensors
Grantee:Jose Luiz Bott Neto
Support Opportunities: Scholarships abroad - Research Internship - Post-doctor
FAPESP's process: 18/22214-6 - Towards a convergence of technologies: from sensing and biosensing to information visualization and machine learning for data analysis in clinical diagnosis
Grantee:Osvaldo Novais de Oliveira Junior
Support Opportunities: Research Projects - Thematic Grants
FAPESP's process: 19/13514-9 - Electrochemical sensors with a matrix containing graphene quantum dots or nanoribbons for the detection of biomarkers
Grantee:Jose Luiz Bott Neto
Support Opportunities: Scholarships in Brazil - Post-Doctoral
FAPESP's process: 22/15122-3 - Developing new breathable tattoo (bio)sensors for health monitoring
Grantee:Thiago Serafim Martins
Support Opportunities: Scholarships abroad - Research Internship - Post-doctor