| Full text | |
| Author(s): |
da Silva, Rodrigo C.
[1]
;
da Silva, Gustavo P.
[1]
;
Sangi, Diego P.
[2, 1]
;
Pontes, Joao G. de M.
[1]
;
Ferreira, Antonio G.
[1]
;
Correa, Arlene G.
[1]
;
Paixao, Marcio W.
[1]
Total Authors: 7
|
| Affiliation: | [1] Univ Fed Sao Carlos, Dept Quim, BR-13560 Sao Carlos, SP - Brazil
[2] Univ Fed Fluminense, Inst Ciencias Exatas, BR-27213145 Volta Redonda, RJ - Brazil
Total Affiliations: 2
|
| Document type: | Journal article |
| Source: | Tetrahedron; v. 69, n. 43, p. 9007-9012, OCT 28 2013. |
| Web of Science Citations: | 8 |
| Abstract | |
A new class of hydrogen bond donor catalysts based on the 1,1-diamino-2-nitreethylene scaffold has been introduced for the activation of trans-beta-nitrostyrenes toward reactions with a range of carbon-based nucleophiles, affording the corresponding adducts in excellent yields. Importantly, this new set of organocatalysts is easily prepared from commercially available starting materials in mild reaction conditions. (C) 2013 Elsevier Ltd. All rights reserved. (AU) | |
| FAPESP's process: | 09/07281-0 - Asymmetric organocatalysis: design of new organocatalysts and development of new methodologies |
| Grantee: | Márcio Weber Paixão |
| Support Opportunities: | Research Grants - Young Investigators Grants |