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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Electrochemical behavior of a lead-free Sn-Cu solder alloy in NaCl solution

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Author(s):
Osorio, Wislei R. [1, 2] ; Freitas, Emmanuelle S. [2] ; Spinelli, Jose E. [3] ; Garcia, Amauri [2]
Total Authors: 4
Affiliation:
[1] Univ Estadual Campinas, UNICAMP, Sch Appl Sci FCA, BR-13484350 Limeira, SP - Brazil
[2] Univ Estadual Campinas, UN1CAMP, Dept Mat Engn, BR-13083970 Campinas, SP - Brazil
[3] Fed Univ Sao Carlos UFSCar, Dept Mat Engn, BR-13565905 Sao Carlos, SP - Brazil
Total Affiliations: 3
Document type: Journal article
Source: Corrosion Science; v. 80, p. 71-81, MAR 2014.
Web of Science Citations: 20
Abstract

Electrochemical impedance spectroscopy (EIS), potentiodynamic polarization techniques and an equivalent circuit analysis are used to evaluate the electrochemical corrosion behavior of Sn-Cu alloy samples in a naturally aerated 0.5 M NaCl solution at 25 degrees C It has been found that a better electrochemical corrosion resistance is provided by a coarser cellular microstructure array. It has also been found that the corrosion current density (i(corr)) is of about a quarter when compared with that of the finest microstructure examined. Such behavior is attributed to both localized strains between the Sn-rich phase and intermetallic (IMC) particles and the cathode/anode area ratios. The effect of copper alloying on i(corr), is also discussed. (C) 2013 Elsevier Ltd. All rights reserved. (AU)

FAPESP's process: 13/15478-3 - Interrelation of Solidification Thermal and Microstructural Parameters and Tribocorrosive Behavior of Al-Zn(Mg) e Zn-Mg Alloys
Grantee:Emmanuelle Sá Freitas Feitosa
Support Opportunities: Scholarships in Brazil - Post-Doctoral