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(Reference retrieved automatically from SciELO through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Efficient photoelectrochemical reduction of nitrite to ammonium and nitrogen containing gaseous species using Ti/TiO2 nanotube electrodes

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Author(s):
Fabiana A. Sayão [1] ; Luciana Nuñez [2] ; Maria V. B. Zanoni [3]
Total Authors: 3
Affiliation:
[1] Universidade Estadual Paulista Júlio de Mesquita Filho. Instituto de Química de Araraquara - Brasil
[2] Universidade Estadual Paulista Júlio de Mesquita Filho. Instituto de Química de Araraquara - Brasil
[3] Univ Estadual Paulista Julio de Mesquita Filho UN, Inst Quim Araraquara, BR-14800900 Araraquara, SP - Brazil
Total Affiliations: 3
Document type: Journal article
Source: Journal of the Brazilian Chemical Society; v. 25, n. 7, p. 1153-1160, 2014-07-00.
Abstract

The present work describes a suitable method for removing nitrite contaminant from water by using a photoelectrocatalytical method. A Ti/TiO2 nanotube electrode was used as a cathode under UV irradiation and applied potential of -0.2 V vs. Ag/AgCl and it led to 100% of nitrite removal after 6 min of photoelectrolysis conducted in NaCl 7 mmol L-1, pH 7 and in absence of dissolved oxygen. Nitrite reduction on Ti/TiO2 photoelectrodes occurs in the cathodic compartment cell via electrons generated when the electrode is under UV irradiation leading to a generation of 7% of remaining ammonium and 93% nitrogen containing gaseous species after 6 min of treatment. The results indicate that the method could be an efficient tool for the treatment of nitrite in water containing nitrite. (AU)

FAPESP's process: 08/10449-7 - Assessment of occurrence, toxicity/genotoxicity and degradation processes of dyes in effluents and surface water
Grantee:Maria Valnice Boldrin
Support Opportunities: Research Projects - Thematic Grants