Asymmetric organocatalysis: design of new organocatalysts and development of new methodologies

• Grant number: 09/07281-0
• Support Opportunities: Research Grants - Young Investigators Grants
• Start date: November 01, 2009
• End date: October 31, 2013
• Field of knowledge: Physical Sciences and Mathematics - Chemistry - Organic Chemistry
• Principal Investigator: Márcio Weber Paixão
• Grantee: Márcio Weber Paixão
• Host Institution: Centro de Ciências Exatas e de Tecnologia (CCET). Universidade Federal de São Carlos (UFSCAR). São Carlos , SP, Brazil
• Associated scholarship(s): 12/04986-5 - Asymmetric Organocatalysis: Development of New Methodologies and Application in Total Synthesis, BP.PD; 11/01055-8 - Organocatalysis: an excellent tool for the synthesis of bioactive molecules, BP.PD; 10/10855-5 - Synthesis of Triazole and Structural Analysis of Organochalcogen Triazolics Compounds, BP.DR; + associated scholarships 11/01113-8 - Synthesis and Biological Evaluation of 1,4- and 1,5-disubstituted Triazoles Library, BP.IC; 10/07664-3 - Synthesis and Application of Organocatalysts in Asymmetric Epoxidation Reactions in Order to Synthesis of Pheromones, BP.DR; 09/14352-0 - Asymmetric organocatalysis: design of new organocatalysts and development of new methodologies, BP.JP - associated scholarships

Scientific publications

(20)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

SCHWAB, RICARDO S.; SOARES, LETIERE C.; DORNELLES, LUCIANO; RODRIGUES, OSCAR E. D.; PAIXAO, MARCIO W.; GODOI, MARCELO; BRAGA, ANTONIO L.. Chiral Chalcogen Peptides as Ligands for the Catalytic Enantioselective Aryl Transfer Reaction to Aldehydes. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, n. 19, p. 3574-3578, JUL 2010. (09/14352-0, 09/07281-0)

DEOBALD, ANNA M.; CAMARGO, LEANDRO R. S.; ALVES, DIEGO; ZUKERMAN-SCHPECTOR, JULIO; CORREA, ARLENE G.; PAIXAO, MARCIO W.. Click Chemistry: An Efficient Synthesis of Heterocycles Substituted with Steroids, Saponins, and Digitalis Analogues. SYNTHESIS-STUTTGART, n. 24, p. 4003-4010, DEC 2011. (09/07281-0)

SARAIVA, MAIARA T.; SEUS, NATALIA; DE SOUZA, DIEGO; RODRIGUES, OSCAR E. D.; PAIXAO, MARCIO W.; JACOB, RAQUEL G.; LENARDAO, EDER J.; PERIN, GELSON; ALVES, DIEGO. Synthesis of [(Arylselanyl)alkyl]-1,2,3-triazoles by Copper-Catalyzed 1,3-Dipolar Cycloaddition of (Arylselanyl)alkynes with Benzyl Azides. SYNTHESIS-STUTTGART, v. 44, n. 13, p. 1997-2004, JUL 2012. (09/07281-0)

ALI, AKBAR; CORREA, ARLENE G.; ALVES, DIEGO; ZUKERMAN-SCHPECTOR, JULIO; WESTERMANN, BERNHARD; FERREIRA, MARCO A. B.; PAIXAO, MARCIO W.. An efficient one-pot strategy for the highly regioselective metal-free synthesis of 1,4-disubstituted-1,2,3-triazoles. CHEMICAL COMMUNICATIONS, v. 50, n. 80, p. 11926-11929, 2014. (13/02311-3, 09/54040-8, 09/07281-0)

ECHEMENDIA, RADELL; CONCEPCION, ODETTE; MORALES, FIDEL E.; PAIXAO, MARCIO W.; RIVERA, DANIEL G.. The Cu-I-catalyzed alkyne-azide cycloaddition as direct conjugation/cyclization method of peptides to steroids. Tetrahedron, v. 70, n. 20, p. 3297-3305, MAY 20 2014. (09/07281-0)

DEOBALD, ANNA MARIA; CORREA, ARLENE G.; RIVERA, DANIEL G.; PAIXAO, MARCIO WEBER. Organocatalytic asymmetric epoxidation and tandem epoxidation/Passerini reaction under eco-friendly reaction conditions. ORGANIC & BIOMOLECULAR CHEMISTRY, v. 10, n. 38, p. 7681-7684, 2012. (09/07281-0)

DA SILVA, RODRIGO C.; DA SILVA, GUSTAVO P.; SANGI, DIEGO P.; PONTES, JOAO G. DE M.; FERREIRA, ANTONIO G.; CORREA, ARLENE G.; PAIXAO, MARCIO W.. 1,1-Diamino-2-nitroethylenes as excellent hydrogen bond donor organocatalysts in the Michael addition of carbon-based nucleophiles to beta-nitrostyrenes. Tetrahedron, v. 69, n. 43, p. 9007-9012, OCT 28 2013. (09/07281-0)

GODOI, MARCELO; RICARDO, EDUARDO W.; FRIZON, TIAGO E.; ROCHA, MANUELA S. T.; SINGH, DEVENDER; PAIXAO, MARCIO W.; BRAGA, ANTONIO LUIZ. An efficient synthesis of alkynyl selenides and tellurides from terminal acetylenes and diorganyl diselenides or ditellurides catalyzed by recyclable copper oxide nanopowder. Tetrahedron, v. 68, n. 51, p. 10426-10430, DEC 23 2012. (09/07281-0)

GODOI, MARCELO; PAIXAO, MARCIO W.; BRAGA, ANTONIO L.. Chiral organoselenium-transition-metal catalysts in asymmetric transformations. DALTON TRANSACTIONS, v. 40, n. 43, p. 11347-11355, 2011. (09/07281-0)

SCHWAB, RICARDO S.; SOARES, LETIERE C.; DORNELLES, LUCIANO; RODRIGUES, OSCAR E. D.; PAIXAO, MARCIO W.; GODOI, MARCELO; BRAGA, ANTONIO L.. Chiral Chalcogen Peptides as Ligands for the Catalytic Enantioselective Aryl Transfer Reaction to Aldehydes. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, v. 2010, n. 19, p. 5-pg., 2010-07-01. (09/14352-0, 09/07281-0)

DEOBALD, ANNA M.; CAMARGO, LEANDRO R. S.; ALVES, DIEGO; ZUKERMAN-SCHPECTOR, JULIO; CORREA, ARLENE G.; PAIXAO, MARCIO W.. Click Chemistry: An Efficient Synthesis of Heterocycles Substituted with Steroids, Saponins, and Digitalis Analogues. SYNTHESIS-STUTTGART, v. N/A, n. 24, p. 8-pg., 2011-12-01. (09/07281-0)

LIMA, CAROLINA G. S.; SILVA, SANDRINA; GONCALVES, RICARDO H.; LEITE, EDSON R.; SCHWAB, RICARDO S.; CORREA, ARLENE G.; PAIXAO, MARCIO W.. Highly Efficient and Magnetically Recoverable Niobium Nanocatalyst for the Multicomponent Biginelli Reaction. CHEMCATCHEM, v. 6, n. 12, p. 3455-3463, DEC 2014. (12/04986-5, 13/06558-3, 09/07281-0)

DIEGO P. SANGI; JULIA L. MONTEIRO; KENIA L. VANZOLINI; QUEZIA B. CASS; MARCIO W. PAIXÃO; ARLENE G. CORRÊA. Microwave-assisted synthesis of N-heterocycles and their evaluation using an acetylcholinesterase immobilized capillary reactor. Journal of the Brazilian Chemical Society, v. 25, n. 5, p. 887-889, 2014-05-00. (09/07281-0, 09/54040-8)

DE LA TORRE, ALEXANDER F.; RIVERA, DANIEL G.; FERREIRA, MARCO A. B.; CORREA, ARLENE G.; PAIXAO, MARCIO W.. Multicomponent Combinatorial Development and Conformational Analysis of Prolyl Peptide-Peptoid Hybrid Catalysts: Application in the Direct Asymmetric Michael Addition. Journal of Organic Chemistry, v. 78, n. 20, p. 10221-10232, OCT 18 2013. (13/02311-3, 09/07281-0)

NARAYANAPERUMAL, SENTHIL; RIVERA, DANIEL G.; SILVA, RODRIGO C.; PAIXAO, MARCIO W.. Terpene-Derived Bifunctional Thioureas in Asymmetric Organocatalysis. CHEMCATCHEM, v. 5, n. 10, p. 2756-2773, OCT 2013. (11/01055-8, 09/07281-0)

FEU, KARLA SANTOS; DEOBALD, ANNA MARIA; NARAYANAPERUMAL, SENTHIL; CORREA, ARLENE G.; PAIXAO, MARCIO WEBER. An Eco-Friendly Asymmetric Organocatalytic Conjugate Addition of Malonates to ,-Unsaturated Aldehydes: Application on the Synthesis of Chiral Indoles. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, v. 2013, n. 26, p. 5917-5922, SEP 2013. (09/07281-0)

SEUS, NATALIA; GONCALVES, LOREN C.; DEOBALD, ANNA M.; SAVEGNAGO, LUCIELLI; ALVES, DIEGO; PAIXAO, MARCIO W.. Synthesis of arylselanyl-1H-1,2,3-triazole-4-carboxylates by organocatalytic cycloaddition of azidophenyl arylselenides with beta-keto-esters. Tetrahedron, v. 68, n. 51, p. 10456-10463, DEC 23 2012. (09/07281-0)

FEU, KARLA S.; DE LA TORRE, ALEXANDER F.; SILVA, SANDRINA; DE MORAES JUNIOR, MARCO A. F.; CORREA, ARLENE G.; PAIXAO, MARCIO W.. Polyethylene glycol (PEG) as a reusable solvent medium for an asymmetric organocatalytic Michael addition. Application to the synthesis of bioactive compounds. GREEN CHEMISTRY, v. 16, n. 6, p. 3169-3174, 2014. (12/04986-5, 09/07281-0)

NARAYANAPERUMAL, SENTHIL; DA SILVA, RODRIGO CESAR; FEU, KARLA SANTOS; DE LA TORRE, ALEXANDER FERNANDEZ; CORREA, ARLENE G.; PAIXAO, MARCIO WEBER. Basic-functionalized recyclable ionic liquid catalyst: A solvent-free approach for Michael addition of 1,3-dicarbonyl compounds to nitroalkenes under ultrasound irradiation. ULTRASONICS SONOCHEMISTRY, v. 20, n. 3, p. 793-798, MAY 2013. (11/01055-8, 09/07281-0)

NARAYANAPERUMAL, SENTHIL; DA SILVA, RODRIGO CESAR; MONTEIRO, JULIA L.; CORREA, ARLENE G.; PAIXAO, MARCIO W.. Iron(III) chloride catalyzed glycosylation of peracylated sugars with allyl/alkynyl alcohols. Journal of the Brazilian Chemical Society, v. 23, n. 11, p. 1982-1988, NOV 2012. (09/07281-0)