Syntheses and characterization of nanozeolites-enzymes complexes and their use as heterogeneous catalysts in the production of biodiesel by trans esterification of Palm Oil and algae oils (Dunaliella Salina and Haematococcus pluvialis) with ethanol

• Grant number: 11/51851-5
• Support Opportunities: Regular Research Grants
• Start date: July 01, 2013
• End date: August 31, 2015
• Field of knowledge: Physical Sciences and Mathematics - Chemistry - Inorganic Chemistry
• Principal Investigator: Jose Geraldo Nery
• Grantee: Jose Geraldo Nery
• Host Institution: Instituto de Biociências, Letras e Ciências Exatas (IBILCE). Universidade Estadual Paulista (UNESP). Campus de São José do Rio Preto. São José do Rio Preto , SP, Brazil

Abstract

The possibility of using synthetic zeolites as inorganic solid supports for the immobilization of enzymes has open an window of opportunities to prepare alternative heterogeneous catalysts that combine the main advantages of enzymatic catalysts with those of the zeolitic catalysts. Although there are several studies in the literature describing the immobilization and the physic -chemical and catalytic behavior of lipases from different sources on micrometric zeolites of different | crystallographic strucutures, a careful review of the literature will show a lack of information about the use of nanozeolites as inorganic solid support for the immobilization of lipases and the application of these complexes nanozeolites-enzymes as catalyst for the production of biodiesel by transesterification reaction of vegetable oils with ethanol. The main goal of this research project is the syntheses of several and different nanaozeolites of different crystallographic structures such as BEA, FAU, LTA, MFI, TS-1 zeolites and their use as inorganic solid support for the immobilization of different lipases enzymes. The lipases enzymes that will be immobilized will be from different sources and the main ones are Rhizomucor meihei, Thermomyces lanuginosos, Candida antarctica, Burkholderia cepacia. These new nanozeolites-enzymes complexes will be characterized by XRD, NMR-MAS, FT-IR, AFM and will tested for biodiesel production by the transesterification of Palm oil and algae oils (Dunaliella Salina e Haematococcus pluvialis) with ethanol. (AU)

Scientific publications

(11)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

MEDEIROS, VINICIUS LITRENTA; DE ARAUJO, LEANDRO GOULART; RATERO, DAVI RUBINHO; PAULA, ALEX SILVA; MOLINA, EDUARDO FERREIRA; JAEGER, CHRISTIAN; MARUMO, JULIO TAKEHIRO; NERY, JOSE GERALDO. Synthesis and physicochemical characterization of a novel adsorbent based on yttrium silicate: A potential material for removal of lead and cadmium from aqueous media. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, v. 8, n. 4, AUG 2020. (11/51851-5, 19/01858-5)

DA SILVA, DANILO ANTONIO; SANTISTEBAN, OSCAR A. N.; DE VASCONCELLOS, ADRIANO; PAULA, ALEX SILVA; ARANDA, DONATO A. G.; GIOTTO, MARCUS VINICIUS; JAEGER, CHRISTIAN; NERY, JOSE G.. Metallo-stannosilicate heterogeneous catalyst for biodiesel production using edible, non-edible and waste oils as feedstock. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, v. 6, n. 4, p. 5488-5497, AUG 2018. (11/51851-5)

PAULA, ALEX SILVA; POSSATO, GUSTAVO; RATERO, DAVI RUBINHO; CONTRO, JANINE; KEINAN-ADAMSKY, KEREN; SOARES, RICARDO REIS; GOOBES, GIL; MARTINS, LEANDRO; NERY, JOSE G.. One-step oxidehydration of glycerol to acrylic acid using ETS-10-like vanadosilicates. Microporous and Mesoporous Materials, v. 232, p. 151-160, SEP 15 2016. (11/51851-5, 10/01449-3, 05/54703-6)

DE VASCONCELLOS, ADRIANO; LAURENTI, JULIANA BERGAMASCO; MILLER, ALEX HENRIQUE; DA SILVA, DANILO ANTONIO; DE MORAES, FABIO ROGERIO; ARANDA, DONATO A. G.; NERY, JOSE G.. Potential new biocatalysts for biofuel production: The fungal lipases of Thermomyces lanuginosus and Rhizomucor miehei immobilized on zeolitic supports ion exchanged with transition metals. Microporous and Mesoporous Materials, v. 214, p. 166-180, SEP 15 2015. (11/10092-4, 11/51851-5)

DA SILVA, DANILO ANTONIO; GREISER, SEBASTIAN; CONTRO, JANINE; MEDEIROS, VINICIUS LITRENTA; NERY, JOSE GERALDO; JAEGER, CHRISTIAN. H-1, Si-29 and Sn-119 double and triple resonance NMR spectroscopy of the small-pore framework sodium stannosilicate Na2SnSi3O9 center dot 2H(2)O. SOLID STATE NUCLEAR MAGNETIC RESONANCE, v. 107, JUN 2020. (11/51851-5)

CONTRO, JANINE; PAULA, ALEX S.; MEDEIROS, VINICIUS LITRENTA; RODRIGUES, ARIANO D.; PACHECO, CARLOS; NERY, JOSE G.. Synthesis of ETS-10-like vanadosilicates using 2,6-dimethylpiperidinium cation derivatives as organic templates. Inorganic Chemistry Communications, v. 112, FEB 2020. (05/54703-6, 11/51851-5)

LUIZON FILHO, ROBERTO A.; POSSATO, LUIZ G.; SANTISTEBAN, OSCAR A. N.; DE VASCONCELLOS, ADRIANO; DA SILVA, DANILO A.; LIMA, MARCELO F.; MARTINS, LEANDRO; NERY, JOSE G.. Synthesis and characterization of chromium silicate catalyst and its application in the gas phase glycerol transformation into acetaldehyde. Inorganic Chemistry Communications, v. 112, FEB 2020. (18/01258-5, 11/51851-5, 18/17588-4)

DE VASCONCELLOS, ADRIANO; MILLER, ALEX HENRIQUE; ARANDA, DONATO A. G.; NERY, JOSE GERALDO. Biocatalysts based on nanozeolite-enzyme complexes: Effects of alkoxysilane surface functionalization and biofuel production using microalgae lipids feedstock. COLLOIDS AND SURFACES B-BIOINTERFACES, v. 165, p. 150-157, MAY 1 2018. (12/24259-0, 11/10092-4, 11/51851-5, 16/24303-0)

BERGAMASCO, JULIANA; DE ARAUJO, MARCELO V.; DE VASCONCELLOS, ADRIANO; LUIZON FILHO, ROBERTO A.; HATANAKA, RAFAEL R.; GIOTTO, MARCUS V.; ARANDA, DONATO A. G.; NERY, JOSE G.. Enzymatic transesterification of soybean oil with ethanol using lipases immobilized on highly crystalline PVA microspheres. BIOMASS & BIOENERGY, v. 59, p. 218-233, DEC 2013. (11/10092-4, 11/51851-5, 05/54703-6)

MEDEIROS, VINICIUS LITRENTA; DE ARAUJO, LEANDRO GOULART; RATERO, DAVI RUBINHO; PAULA, ALEX SILVA; MOLINA, EDUARDO FERREIRA; JAEGER, CHRISTIAN; MARUMO, JULIO TAKEHIRO; NERY, JOSE GERALDO. Synthesis and physicochemical characterization of a novel adsorbent based on yttrium silicate: A potential material for removal of lead and cadmium from aqueous media. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, v. 8, n. 4, p. 10-pg., 2020-08-01. (11/51851-5, 19/01858-5)

DA SILVA, DANILO ANTONIO; SANTISTEBAN, OSCAR A. N.; DE VASCONCELLOS, ADRIANO; PAULA, ALEX SILVA; ARANDA, DONATO A. G.; GIOTTO, MARCUS VINICIUS; JAEGER, CHRISTIAN; NERY, JOSE G.. Metallo-stannosilicate heterogeneous catalyst for biodiesel production using edible, non-edible and waste oils as feedstock. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, v. 6, n. 4, p. 10-pg., 2018-08-01. (11/51851-5)