Multifunctional molecular magnetic systems: synthesis and study of magnetic, luminescent and photorreactive properties of polinuclear complexes containing transition and lanthanide metal ions

• Grant number: 15/22379-7
• Support Opportunities: Regular Research Grants
• Start date: June 01, 2016
• End date: May 31, 2018
• Field of knowledge: Physical Sciences and Mathematics - Chemistry - Inorganic Chemistry
• Principal Investigator: Wdeson Pereira Barros
• Grantee: Wdeson Pereira Barros
• Host Institution: Instituto de Química (IQ). Universidade Estadual de Campinas (UNICAMP). Campinas , SP, Brazil

Abstract

This project rely on the preparation of molecular systems containing transition and lanthanide metal ions associated with oxamate ligands and auxiliary ligands that contain N- and/or O-donor sites to enable the interaction between several building blocks. The use of transition and lanthanide metal ions are important for magnetic and luminescent properties in the proposed systems. Moreover, the auxiliary ligands make room for the preparation of homo- and heterometallic systems that could lead to the formation of Metalorganic Frameworks with many dimensionalities. Another appealing mark of the auxiliary ligands to be prepared is the presence of photorreactive groups that could be able to change the magnetic interactions between the metal ions according to the range of the light spectrum irradiation over the systems. Thus, we expect to explore the formation of Metalorganic Frameworks and establish a correlation between the structure and photomagnetic and luminescent properties, contributing for the development of new multifunctional materials. (AU)

Scientific publications

(6)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

REIS, V, NATALIA; MARINHO, MARIA VANDA; SIMOES, TATIANA RENATA G.; METZ, KARINA C.; VAZ, RAPHAEL C. A.; OLIVEIRA, WILLIAN X. C.; PEREIRA, CYNTHIA L. M.; BARROS, WDESON P.; PINHEIRO, CARLOS B.; GIESE, SIDDHARTHA O. K.; et al. Structural versatility driven by the flexible di(4-pyridyl) sulfide ligand: From cobalt(II) single-ion magnets to sheet-like copper(II) weak antiferromagnets. Polyhedron, v. 171, p. 203-211, OCT 1 2019. (15/22379-7)

REIS, NATALIA V.; BARROS, WDESON P.; OLIVEIRA, WILLIAN X. C.; PEREIRA, CYNTHIA L. M.; ROCHA, WILLIAN R.; PINHEIRO, CARLOS B.; LLORET, FRANCESC; JULVE, MIGUEL; STUMPF, HUMBERTO O.. Crystal Structure and Magnetic Properties of an Oxamato-Bridged Heterobimetallic Tetranuclear [(NiCuII)-Cu-II](2) Complex of the Rack Type. European Journal of Inorganic Chemistry, n. 3-4, SI, p. 477-484, JAN 31 2018. (15/22379-7)

DEZOTTI, YURI; RIBEIRO, MARCOS ANTONIO; PIROTA, KLEBER R.; BARROS, WDESON PEREIRA. Influence of the Metal Ion on the Topology and Interpenetration of Pyridylvinyl(benzoate) Based Metal-Organic Frameworks. Crystal Growth & Design, v. 19, n. 10, p. 5592-5603, OCT 2019. (15/22379-7)

SILVA, INGRID F.; TEIXEIRA, IVO F.; BARROS, WDESON P.; PINHEIRO, CARLOS B.; ARDISSON, JOSE D.; DO NASCIMENTO, GUSTAVO M.; PRADIE, NORIBERTO A.; TEIXEIRA, ANA PAULA C.; STUMPF, HUMBERTO O.. An Fe-III dinuclear metallacycle complex as a size-selective adsorbent for nitrogenous compounds and a potentially effective ammonia storage material. JOURNAL OF MATERIALS CHEMISTRY A, v. 7, n. 25, p. 15225-15232, JUL 7 2019. (15/22379-7, 17/05506-0)

ALCANTARA, ARTHUR F. P.; FONTANA, LINIQUER A.; RIGOLIN, VITOR H.; ANDRADE, YURI F. S.; RIBEIRO, MARCOS A.; BARROS, WDESON P.; ORNELAS, CATIA; MEGIATTO, JR., JACKSON D.. Olefin Cyclopropanation by Radical Carbene Transfer Reactions Promoted by Cobalt(II)/Porphyrinates: Active-Metal-Template Synthesis of [2]Rotaxanes. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v. 57, n. 29, p. 8979-8983, JUL 16 2018. (15/23761-2, 13/22160-0, 15/22379-7, 17/06752-5)

REIS, NATALIA V.; BARROS, WDESON P.; OLIVEIRA, WILLIAN X. C.; PEREIRA, CYNTHIA L. M.; ROCHA, WILLIAN R.; PINHEIRO, CARLOS B.; LLORET, FRANCESC; JULVE, MIGUEL; STUMPF, HUMBERTO O.. Crystal Structure and Magnetic Properties of an Oxamato-Bridged Heterobimetallic Tetranuclear [(NiCuII)-Cu-II](2) Complex of the Rack Type. European Journal of Inorganic Chemistry, v. N/A, n. 3-4, p. 8-pg., 2018-01-31. (15/22379-7)