Synthesis and characterization of biopolymers from vegetable oils and glycerol following the principles of green chemistry

• Grant number: 17/08820-8
• Support Opportunities: Regular Research Grants
• Start date: February 01, 2018
• End date: May 31, 2020
• Field of knowledge: Engineering - Materials and Metallurgical Engineering - Nonmetallic Materials
• Principal Investigator: Gilbert Bannach
• Grantee: Gilbert Bannach
• Host Institution: Faculdade de Ciências (FC). Universidade Estadual Paulista (UNESP). Campus de Bauru. Bauru , SP, Brazil
• Associated researchers: JAMES VENTURINI ; Luiz Carlos da Silva Filho

Abstract

The objectives of this project are synthesis and characterization of new polymers following principles of green chemistry, using industrial wastes (glycerol), several vegetable oils such as babassu, soybean, grape, macauba and sunflower; and low cost reagents as maleic anhydride. An important point in this project is add value to bio-commodities produced in Brazil. Simultaneous Thermogravimetric/Derivative Thermogravimetry-Differential Thermal Analysis (TG/DTG-DTA), Differential Scanning Calorimetry (DSC) will characterize the synthesized polymers. Complementary studies will be made by Scanning Electron Microscopy (SEM), Fourier Transform Infrared Spectroscopy (FTIR), X-Ray diffraction (XRD), Nuclear Magnetic Resonance (NMR 1H and 13C), High Resolution Mass Spectrometry (HRMS) as well as inherent viscosity, density and solvent resistance. Hence, after characterization will be possible propose applications for the synthesized polymers. (AU)

Scientific publications

(28)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

ALARCON, RAFAEL TURRA; GAGLIERI, CAROLINE; DOS SANTOS, GIOVANNY CARVALHO; ROLDAO, JUAN CARLOS; MAGDALENA, AROLDO GERALDO; DA SILVA-FILHO, LUIZ CARLOS; BANNACH, GILBERT. A deep investigation into the thermal degradation of urethane dimethacrylate polymer. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, APR 2021. (18/03460-6, 15/00615-0, 16/01599-1, 17/08820-8, 18/14506-7)

PIEDADE, LUCAS PEREIRA; PINTAO, CARLOS ALBERTO FONZAR; FOSCHINI, CESAR RENATO; SILVA, MARCOS RIBEIRO DA; AZEVEDO NETO, NILTON FRANCELOSI. Alternative dynamic torsion test to evaluate the elastic modulus of polymers. MATERIALS RESEARCH EXPRESS, v. 7, n. 9, SEP 2020. (07/04094-9, 17/08820-8)

BIM-JUNIOR, ODAIR; GAGLIERI, CAROLINE; BEDRAN-RUSSO, ANA K.; BUENO-SILVA, BRUNO; BANNACH, GILBERT; FREM, REGINA; XIMENES, VALDECIR FARIAS; LISBOA-FILHO, PAULO N.. MOF-Based Erodible System for On-Demand Release of Bioactive Flavonoid at the Polymer-Tissue Interface. ACS BIOMATERIALS SCIENCE & ENGINEERING, v. 6, n. 8, p. 4539-4550, AUG 2020. (17/08820-8, 14/50926-0, 18/02186-8)

DEMARIO VIEIRA, RENATA LEIA; GAGLIERI, CAROLINE; DE OLIVEIRA, CRISTINA SOLTOVSKI; FERREIRA, LAURA TEOFILO; SCHNITZLER, EGON; BANNACH, GILBERT. Effect of the milling process on the thermal behavior and crystallinity of buckwheat starch. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, v. 144, n. 3, MAR 2020. (17/08820-8)

GAGLIERI, CAROLINE; DE MOURA, ANIELE; ALARCON, RAFAEL T.; MAGRI, RAQUEL; BANNACH, GILBERT. Thermal behavior of some cyclic anhydrides: an important characterization for synthesis in the polymer field. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, v. N/A, p. 12-pg., 2022-01-23. (20/00906-3, 18/03460-6, 17/08820-8)

HOLANDA, BRUNO B. C.; ALARCON, RAFAEL T.; GUERRA, RENAN B.; RINALDO, DANIEL; SPAZZINI, FABIOLA C. R.; CASTRO, RICARDO A. E.; BANNACH, GILBERT. Investigation of thermal degradation products of mebendazole by thermal and spectroscopic analysis. JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, v. 135, p. 76-84, OCT 2018. (18/03460-6, 17/08820-8)

ESTEVAM DA SILVA, JOSE EDUARDO; ALARCON, RAFAEL TURRA; GAGLIERI, CAROLINE; MAGDALENA, AROLDO GERALDO; DA SILVA-FILHO, LUIZ CARLOS; BANNACH, GILBERT. New thermal study of polymerization and degradation kinetics of methylene diphenyl diisocyanate. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, v. 133, n. 3, p. 1455-1462, SEP 2018. (17/08820-8, 13/09022-7)

BALDO PIRES, OSMAR ANTONIO; ALARCON, RAFAEL TURRA; GAGLIERI, CAROLINE; DA SILVA-FILHO, LUIZ CARLOS; BANNACH, GILBERT. Synthesis and characterization of a biopolymer of glycerol and macadamia oil. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, v. 137, n. 1, p. 161-170, JUL 2019. (17/08820-8, 15/00615-0, 16/01599-1, 18/03460-6, 13/09022-7)

ALARCON, RAFAEL TURRA; DOS SANTOS, GIOVANNY CARVALHO; DE OLIVEIRA, ARTHUR ROSSI; DA SILVA-FILHO, LUIZ CARLOS; BANNACH, GILBERT. Synthesis of luminescent polymers in the UV light region from dimethacrylate monomer using novel quinoline dyes. Journal of Applied Polymer Science, v. 136, n. 19, MAY 15 2019. (13/09022-7, 18/03460-6, 16/01599-1, 18/14506-7, 15/00615-0, 17/08820-8)

ALARCON, RAFAEL TURRA; GAGLIERI, CAROLINE; DOS SANTOS, GIOVANNY CARVALHO; ROLDAO, JUAN CARLOS; MAGDALENA, AROLDO GERALDO; DA SILVA-FILHO, LUIZ CARLOS; BANNACH, GILBERT. A deep investigation into the thermal degradation of urethane dimethacrylate polymer. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, v. 147, n. 4, p. 3083-3097, FEB 2022. (16/01599-1, 17/08820-8, 18/03460-6, 18/14506-7, 15/00615-0)

MAGRI, RAQUEL; GAGLIERI, CAROLINE; ALARCON, RAFAEL T.; BANNACH, GILBERT. Epoxidation reaction in promising Brazilian biomass: decreased time and catalyst loading to produce renewable monomers. JOURNAL OF POLYMER RESEARCH, v. 28, n. 9, SEP 2021. (18/03460-6, 20/00906-3, 17/08820-8)

ALARCON, RAFAEL T.; LAMB, KATIE J.; BANNACH, GILBERT; NORTH, MICHAEL. Opportunities for the Use of Brazilian Biomass to Produce Renewable Chemicals and Materials. CHEMSUSCHEM, v. 14, n. 1, p. 169-188, JAN 7 2021. (18/03460-6, 17/08820-8, 19/11493-4)

GUERRA, RENAN B.; DE CAMPOS FRAGA-SILVA, THAIS FERNANDA; AGUIAR, JULIA; OSHIRO, PAULA B.; HOLANDA, BRUNO B. C.; VENTURINI, JAMES; BANNACH, GILBERT. Lanthanum(III) and neodymium(III) complexes with anti-inflammatory drug sulindac: Synthesis, characterization, thermal investigation using coupled techniques TG-FTIR, and in vitro biological studies. Inorganica Chimica Acta, v. 503, APR 1 2020. (17/08820-8, 13/04096-2)

GAGLIERI, CAROLINE; ALARCON, RAFAEL T.; DE MOURA, ANIELE; MENDES, RONI A.; CAIRES, FLAVIO J.. Is Thermogravimetry an efficient alternative to gas chromatography in degree of biodiesel conversion?. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, v. 135, n. 4, p. 2591-2597, FEB 2019. (17/14936-9, 17/08820-8)

FERREIRA, LAURA TEOFILO; ALARCON, RAFAEL TURRA; PERPETUO, GLAUCO LINI; BANNACH, GILBERT. Investigation and characterization by TG/DTG-DTA and DSC of the fusion of Riboflavin, and its interaction with the antibiotic norfloxacin in the screening of cocrystal. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, v. 136, n. 2, p. 581-588, APR 2019. (13/09022-7, 18/03460-6, 17/08820-8)

HOLANDA, BRUNO B. C.; BANNACH, GILBERT; SILVA, M. RAMOS; EUSEBIO, M. ERMELINDA S.; CASTRO, RICARDO A. E.. Polymorphism of gemfibrozil: Investigation by thermal and spectroscopic methods. Thermochimica Acta, v. 675, p. 113-118, MAY 2019. (17/08820-8)

ALARCON, RAFAEL TURRA; GAGLIERI, CAROLINE; DE OLIVEIRA, ARTHUR ROSSI; BANNACH, GILBERT. Use of DSC in degree of conversion of dimethacrylate polymers: easier and faster than MIR technique. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, v. 132, n. 2, p. 1423-1427, MAY 2018. (17/08820-8, 13/09022-7)

CARLOS ALBERTO FONZAR PINTÃO; LUCAS PEREIRA PIEDADE; EDGAR BORALI. System to measure torsion modulus of polymers using the deformation energy method. POLIMEROS-CIENCIA E TECNOLOGIA, v. 29, n. 3, 2019-08-01. (07/04094-9, 17/08820-8)

ALARCON, RAFAEL T.; GAGLIERI, CAROLINE; DE SOUZA, OTAVIO A.; RINALDO, DANIEL; BANNACH, GILBERT. Microwave-Assisted Syntheses of Vegetable Oil-Based Monomer: A Cleaner, Faster, and More Energy Efficient Route. JOURNAL OF POLYMERS AND THE ENVIRONMENT, v. 28, n. 4, FEB 2020. (18/03460-6, 17/08820-8)

ALARCON, RAFAEL T.; GAGLIERI, CAROLINE; DOS SANTOS, GIOVANNY C.; MORALLES, ANA C.; MORGON, NELSON H.; DE SOUZA, AGUINALDO R.; BANNACH, GILBERT. AIE Effect by Oxygen Clustering in Vegetable Oil-Based Polymers. CHEMISTRYSELECT, v. 6, n. 31, p. 7838-7844, AUG 20 2021. (13/08293-7, 18/03460-6, 17/08820-8, 15/22338-9)

ALARCON, RAFAEL TURRA; GAGLIERI, CAROLINE; BANNACH, GILBERT. Dimethacrylate polymers with different glycerol content. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, v. 132, n. 3, p. 1579-1591, JUN 2018. (17/08820-8, 13/09022-7)

RODRIGUES, EDGAR JUNIO DAMASCENO; DE CARVALHO, PEDRO LUIZ PUCCI FIGUEIREDO; XAVIER, WILLIAM DOS SANTOS; GUIMARAES, MATHEUS GARDIM; VICENTE, IGOR SIMOES TIAGUA; BARROS, MARGARIDA MARIA; SARTORI, MARIA MARCIA PEREIRA; PADILHA, PEDRO DE MAGALHAES; ALARCON, RAFAEL TURRA; GAGLIERI, CAROLINE; et al. Plant-based polymer as a thermoresistant carrier of phytase in Nile tilapia (Oreochromis niloticus) diets. ANIMAL FEED SCIENCE AND TECHNOLOGY, v. 296, p. 6-pg., 2023-01-02. (18/03460-6, 18/19293-1, 17/08820-8)

GAGLIERI, CAROLINE; ALARCON, RAFAEL T.; DE MOURA, ANIELE; MAGRI, RAQUEL; DA SILVA-FILHO, LUIZ C.; BANNACH, GILBERT. Green and Efficient Modification of Grape Seed Oil to Synthesize Renewable Monomers. Journal of the Brazilian Chemical Society, v. 32, n. 11, p. 2120-2131, NOV 2021. (20/00906-3, 17/08820-8, 18/03460-6)

FERREIRA, BEATRIZ B.; HOLANDA, BRUNO B. DA C.; LACERDA, LUIZ G.; SCHNITZLER, EGON; VIEIRA, RENATA L. D.; GAGLIERI, CAROLINE; BANNACH, GILBERT. A compatibility study between rice starch and some non-steroidal anti-inflammatories. Thermochimica Acta, v. 698, APR 2021. (17/08820-8)

ALARCON, RAFAEL T.; GAGLIERI, CAROLINE; LAMB, KATIE J.; NORTH, MICHAEL; BANNACH, GILBERT. Spectroscopic characterization and thermal behavior of baru nut and macaw palm vegetable oils and their epoxidized derivatives. INDUSTRIAL CROPS AND PRODUCTS, v. 154, OCT 15 2020. (17/08820-8, 19/11493-4)

GUERRA, RENAN BARRACH; GALICO, DIOGO ALVES; DE CAMPOS FRAGA-SILVA, THAIS FERNANDA; AGUIAR, JULIA; VENTURINI, JAMES; BANNACH, GILBERT. Rare-earth complexes with anti-inflammatory drug sulindac: Synthesis, characterization, spectroscopic and in vitro biological studies. Inorganica Chimica Acta, v. 526, OCT 1 2021. (17/08820-8, 13/04096-2)

ALARCON, RAFAEL T.; GAGLIERI, CAROLINE; LAMB, KATIE J.; CAVALHEIRO, EDER T. G.; NORTH, MICHAEL; BANNACH, GILBERT. A new acrylated monomer from macaw vegetable oil that polymerizes without external photoinitiators. JOURNAL OF POLYMER RESEARCH, v. 28, n. 11, NOV 2021. (18/03460-6, 17/08820-8)

BENITES, ANA BEATRIZ; ALARCON, RAFAEL T.; GAGLIERI, CAROLINE; LAMB, KATIE J.; BANNACH, GILBERT. Effect of metal oxide fillers in urethane dimethacrylate polymer with glycerol obtained by photopolymerization synthesis. JOURNAL OF POLYMER RESEARCH, v. 27, n. 10, p. 11-pg., 2020-09-28. (17/08820-8, 18/03460-6, 19/11493-4)

Filed patent(s) as a result of this research project