Poly(dimethylsiloxane) based segmented urethanes biomimetic adhesives Based on CO2 fixation

• Grant number: 13/05279-3
• Support Opportunities: Scholarships abroad - Research Internship - Doctorate
• Start date: November 15, 2013
• End date: November 14, 2014
• Field of knowledge: Physical Sciences and Mathematics - Chemistry - Inorganic Chemistry
• Principal Investigator: Ubirajara Pereira Rodrigues Filho
• Grantee: Kelen Menezes Flores Rossi de Aguiar
• Supervisor: Andreas Hartwig
• Host Institution: Instituto de Química de São Carlos (IQSC). Universidade de São Paulo (USP). São Carlos , SP, Brazil
• Institution abroad: Fraunhofer-Gesellschaft, Germany
• Associated to the scholarship: 11/06019-0 - CO2 uptake and synthesis of polyuretanes-polysilicone co-polymers as additives incorporated in ormosils: use on bioactive and ion conducting films, BP.DR

Abstract

This project aims to produce urethanes PDMS derivatives (PDMSUr) with low glass transition temperature, low water uptake, low surface energy and good adhesion properties on glass, titaniun alloys and stainless steel. The synthetic process of PDMSUr involves a green route using carbon dioxide as phosgene substitute often used in traditional routes. These materials will be tested as medical and dental implants. The tests will be performed at IFAM - Fraunhofer Institute for Manufacturing Technology and Advanced Materials (IFAM). Moreover, this kind of material has potential to adhere on glass/aluminiun substrates with adhesion force greater than 2 kg/cm2. These materials can be resistent to impact due to PDMS segments and are environmental friendly. (AU)

Scientific publications

(8)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

DE AGUIARA, KELEN R.; RISCHKA, KLAUS; GAETJEN, LINDA; NOESKE, PAUL-LUDWIG MICHAEL; CAVALCANTI, WELCHY LEITE; RODRIGUES-FILHO, UBIRAJARA P.. Biomimetic PDMS-hydroxyurethane terminated with catecholic moieties for chemical grafting on transition metal oxide-based surfaces. Applied Surface Science, v. 427, n. B, p. 166-175, JAN 1 2018. (13/05279-3, 11/08120-0, 11/06019-0)

GUNTHER, FLORIAN; LIMA, ELTON F. S.; ROSSI DE AGUIAR, KELEN M. F.; BEARZI, JEFFERSON R.; SIMOES, MATEUS B.; SCHNEIDER, RICARDO; BINI, RAFAEL A.; RIBEIRO, SIDNEY J. L.; CHI MAN, MICHEL WONG; RISCHKA, KLAUS; et al. PDMS-urethanesil hybrid multifunctional materials: combining CO2 use and sol-gel processing. Journal of Sol-Gel Science and Technology, v. 95, n. 3, SI, AUG 2020. (11/08120-0, 18/19785-1, 18/15670-5, 13/05279-3, 11/06019-0)

AGUIAR, K. R.; SANTOS, V. G.; EBERLIN, M. N.; RISCHKA, K.; NOESKE, M.; TREMILIOSI-FILHO, G.; RODRIGUES-FILHO, U. P.. Efficient green synthesis of bis(cyclic carbonate) poly(dimethylsiloxane) derivative using CO2 addition: a novel precursor for synthesis of urethanes. RSC ADVANCES, v. 4, n. 46, p. 24334-24343, 2014. (13/05279-3, 11/08120-0, 11/06019-0)

ROSSI DE AGUIAR, K. M. F.; SPECHT, U.; MAASS, J. F.; SALZ, D.; PICON, C. A.; NOESKE, P. -L. M.; RISCHKA, K.; RODRIGUES-FILHO, U. P.. Surface modification by physical treatments on biomedical grade metals to improve adhesion for bonding hybrid non-isocyanate urethanes. RSC ADVANCES, v. 6, n. 53, p. 47203-47211, 2016. (13/05279-3, 11/08120-0, 11/06019-0)

DE AGUIARA, KELEN R.; RISCHKA, KLAUS; GAETJEN, LINDA; NOESKE, PAUL-LUDWIG MICHAEL; CAVALCANTI, WELCHY LEITE; RODRIGUES-FILHO, UBIRAJARA P.. Biomimetic PDMS-hydroxyurethane terminated with catecholic moieties for chemical grafting on transition metal oxide-based surfaces. Applied Surface Science, v. 427, p. 10-pg., 2018-01-01. (13/05279-3, 11/08120-0, 11/06019-0)

GUNTHER, FLORIAN; LIMA, ELTON F. S.; ROSSI DE AGUIAR, KELEN M. F.; BEARZI, JEFFERSON R.; SIMOES, MATEUS B.; SCHNEIDER, RICARDO; BINI, RAFAEL A.; RIBEIRO, SIDNEY J. L.; CHI MAN, MICHEL WONG; RISCHKA, KLAUS; et al. PDMS-urethanesil hybrid multifunctional materials: combining CO2 use and sol-gel processing. Journal of Sol-Gel Science and Technology, v. 95, n. 3, p. 17-pg., 2020-08-10. (11/08120-0, 18/19785-1, 13/05279-3, 11/06019-0, 18/15670-5)

ROSSI DE AGUIAR, KELEN M. F.; NASCIMENTO, V, MATHEUS; FACCIONI, JULIANO L.; NOESKE, PAUL-LUDWIG M.; GAETJEN, LINDA; RISCHKA, KLAUS; RODRIGUES-FILHO, UBIRAJARA P.. Urethanes PDMS-based: Functional hybrid coatings for metallic dental implants. Applied Surface Science, v. 484, p. 1128-1140, AUG 1 2019. (13/05279-3, 11/08120-0, 11/06019-0)

DE AGUIAR, K. M. F. ROSSI; FERREIRA-NETO, E. P.; BLUNK, S.; SCHNEIDER, J. F.; PICON, C. A.; LEPIENSKI, C. M.; RISCHKA, K.; RODRIGUES-FILHO, U. P.. Hybrid urethanesil coatings for inorganic surfaces produced by isocyanate-free and sol-gel routes: synthesis and characterization. RSC ADVANCES, v. 6, n. 23, p. 19160-19172, 2016. (13/05279-3, 11/08120-0, 11/06019-0)