Development of biodegradable polymer blends in urea / melamine / formaldehyde / polyols system for applications as coating of agrochemicals

• Grant number: 18/10448-2
• Support Opportunities: Scholarships in Brazil - Scientific Initiation
• Start date: August 01, 2018
• End date: July 31, 2020
• Field of knowledge: Engineering - Materials and Metallurgical Engineering - Nonmetallic Materials
• Principal Investigator: Cauê Ribeiro de Oliveira
• Grantee: Marisa Gomes da Silva
• Host Institution: Embrapa Instrumentação Agropecuária. Empresa Brasileira de Pesquisa Agropecuária (EMBRAPA). Ministério da Agricultura, Pecuária e Abastecimento (Brasil). São Carlos , SP, Brazil

Abstract

New technological viabilities have aroused interest in the academic and industrial spheres. However, it is desired to focus on sustainable alternatives for the dissemination of new polymer systems derived from vegetable oils, presenting a new approach to reactions, synthesis parameters, structures and chemical properties. Thus, this proposal focuses on preparation of a polymer formulation (in the form of a blend or copolymer) from castor oil (polyol) as a co-reactant in the polymerization process of urea-melamine-formaldehyde resin (UMF). The crosslinking potential between polyol and condensation polymer would increase the plasticity of UMF system by generating a new biodegradable source of N and adequate for fertilizers coating. The materials will be investigated from polycondensation reactions, being characterized by thermal analysis such as thermogravimetry (TG) and differential scanning calorimetry (DSC) as well as Fourier Transform Infrared (FTIR) Spectroscopy. The ability of crosslinking between polyol and UMF system will be investigated in order to understand how the polyol can act as a plasticizer in this system (fragile system). After optimizing the formulations, thin film production and deposition tests will be performed on fertilizer granules, analyzing their ability to act as a barrier to solubilization of agrochemicals.

Scientific publications

(4)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

MAJARON, VINICIUS F.; DA SILVA, MARISA G.; BORTOLETTO-SANTOS, RICARDO; KLAIC, RODRIGO; GIROTO, AMANDA; GUIMARAES, GELTON G. F.; POLITO, WAGNER L.; FARINAS, CRISTIANE S.; RIBEIRO, CAUE. Synergy between castor oil polyurethane/starch polymer coating and local acidification by A. niger for increasing the efficiency of nitrogen fertilization using urea granules. INDUSTRIAL CROPS AND PRODUCTS, v. 154, OCT 15 2020. (16/10636-8, 17/18673-2, 18/10448-2, 18/10104-1, 16/09343-6)

BORTOLETTO-SANTOS, RICARDO; PLOTEGHER, FABIO; MAJARON, VINICIUS F.; DA SILVA, MARISA G.; POLITO, WAGNER L.; RIBEIRO, CAUE. Polyurethane nanocomposites can increase the release control in granulated fertilizers by controlling nutrient diffusion. APPLIED CLAY SCIENCE, v. 199, DEC 1 2020. (18/10448-2, 16/15482-9, 20/03259-9, 16/10636-8, 17/18673-2)

MAJARON, VINICIUS F.; DA SILVA, MARISA G.; PFEIFER, MARCELA; BORTOLETTO-SANTOS, RICARDO; VELLOSO, CAMILA C. V.; KLAIC, RODRIGO; POLITO, WAGNER L.; RIBEIRO, SIDNEY J. L.; BERNARDI, ALBERTO C. C.; FARINAS, CRISTIANE S.; et al. Interaction of Aspergillus niger in Double-Coated Urea Granules Reduces Greenhouse Gas Emissions from N Fertilization. JOURNAL OF SOIL SCIENCE AND PLANT NUTRITION, v. 23, n. 3, p. 10-pg., 2023-05-25. (18/10448-2, 17/18673-2, 20/03259-9, 19/18036-8, 16/10636-8)

MAJARON, VINICIUS F.; DA SILVA, MARISA GOMES; BORTOLETTO-SANTOS, RICARDO; KLAIC, RODRIGO; RIBEIRO, SIDNEY J. L.; POLITO, WAGNER L.; BEVILAQUA, DENISE; FARINAS, CRISTIANE S.; RIBEIRO, CAUE. Bioactive Material with Microorganisms can Enhance the Micronutrients Solubilization and Sulfate Availability from Low Reactive Sources: Insight for Application as Coating Fertilizer Granules. JOURNAL OF POLYMERS AND THE ENVIRONMENT, v. 30, n. 6, p. 12-pg., 2022-01-20. (18/10448-2, 17/18673-2, 20/03259-9)