Synthesis and photovoltaic characterization of thin films based on ferroelectric and multiferroic perovskite for solar cells application

• Grant number: 19/03110-8
• Support Opportunities: Scholarships in Brazil - Post-Doctoral
• Start date: July 01, 2019
• End date: June 30, 2023
• Field of knowledge: Engineering - Materials and Metallurgical Engineering - Nonmetallic Materials
• Principal Investigator: José Antonio Eiras
• Grantee: Mahmoud Saleh Mohammed Alkathy
• Host Institution: Centro de Ciências Exatas e de Tecnologia (CCET). Universidade Federal de São Carlos (UFSCAR). São Carlos , SP, Brazil
• Associated research grant: 17/13769-1 - Multiferroic and ferroelectric materials for energy converters: synthesis, properties, phenomenology and applications, AP.TEM

Abstract

The worldwide energy crisis has motivated the search for new sources of clean and renewable energy, among which the use of the photovoltaic effect for the capture of solar energy has been highlighted. Among various types of materials that can be used for solar cell applications ferroelectric and multiferroic perovskite structures have received great attention in recent years. In this project, thin films of ferroelectric and multiferroic perovskite will be deposited by "RF Sputtering" aiming the optimization of their photovoltaic properties. Among the systems we propose to investigate in this project are complex perovskites of Pb (Fe, B) O3 (B = Nb, W, Ta, Ti) and solid solutions of Pb (Fe, B) O3 - Pb (Zr, Ti) O3, in addition to lead-free perovskites based on K (Na, Nb) O3. The various parameters that influence the photovoltaic effect in these systems, such as band gap, spontaneous/remnant polarization, electrical conductivity, electrode/interface properties, among others, will be investigated by optical, electrical, dielectric and ferroelectric techniques, in macroscopic and nanoscopic scale , aiming at understanding and optimizing the photovoltaic response. In the compositions, in which the absorption band lies the central region of the solar spectrum, the photovoltaic efficiency will be determined in prototypes of solar cells. (AU)

Scientific publications

(22)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

CHAVES, DAVI A. D.; ZABOTTO, FABIO L.; ORTIZ, WILSON A.; GUALDI, ALEXANDRE J.. PMN-PT/NFO magnetoelectric characterization and the advantages of the dynamic stress magnetization model. Ferroelectrics, v. 582, n. 1, p. 12-20, OCT 22 2021. (19/24603-2, 19/03110-8)

NAIR, VISHNU R.; RAMAN, T. S. AKHIL; ALKATHY, MAHMOUD S.; RAJU, K. C. JAMES. Effect of nickel and zinc co-substitution on the structural and dielectric properties of barium titanate ceramics. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, v. 33, n. 17, p. 12-pg., 2022-05-25. (19/03110-8)

ALKATHY, MAHMOUD S.; ZABOTTO, FABIO L.; MILTON, FLAVIO PAULO; EIRAS, J. A.. Achieving high energy storage performance and breakdown strength in modified strontium titanate ceramics. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, v. 33, n. 19, p. 12-pg., 2022-06-07. (19/03110-8, 17/13769-1)

LAVADO, C.; ALKATHY, MAHMOUD. S.; EIRAS, J. A.; STACHIOTTI, M. G.. Room-temperature multiferroic behavior in the three-layer Aurivillius compound Bi3.25La0.75Ti2Nb0.5(Fe1-x Co-x)(0.5)O-12. APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, v. 129, n. 2, p. 10-pg., 2023-02-01. (19/03110-8, 17/13769-1)

ALKATHY, MAHMOUD S.; RAJU, K. C. JAMES; EIRAS, J. A.. Colossal dielectric permittivity and high energy storage efficiency in barium strontium titanate ceramics co-doped with bismuth and lithium. JOURNAL OF PHYSICS D-APPLIED PHYSICS, v. 54, n. 12, MAR 25 2021. (19/03110-8)

VARGAS, NATALIA F. C.; ALKATHY, MAHMOUD S.; EIRAS, JOSE A.; MASTELARO, VALMOR ROBERTO; LENTE, MANUEL H.. Sintering-driven effects on the band gap of (Pb,La)(Ti,Ni)O-3 photovoltaic ceramics. Journal of the American Ceramic Society, v. 104, n. 6, JAN 2021. (19/03110-8, 17/13769-1)

ZABOTTO, FABIO L.; BARBOSA, VITOR F.; PEREIRA, CAROLYNE C. S.; ESTRADA, FLAVIA R.; LENTE, MANUEL H.; CHEN, XIANG MING; EIRAS, JOSE A.. Distinct magnetic contributions for magnetoelectric coupling at room temperature in perovskite PZT-PFN solid solutions. Journal of Alloys and Compounds, v. 929, p. 7-pg., 2022-12-25. (19/16978-6, 19/03110-8, 17/13769-1)

CARVALHO, R. A. R.; BONINI, R. P.; BARBOSA, V. M. F.; BOTERO, E. R.; ALKATHY, MAHMOUD S.; EIRAS, J. A.; ZABOTTO, F. L.. A phenomenological model for the magnetodielectric effect in magnetoelectric composites. Journal of Magnetism and Magnetic Materials, v. 580, p. 5-pg., 2023-06-07. (19/03110-8, 20/06570-7)

BONINI, RICARDO PEREIRA; GUALDI, ALEXANDRA JOSE; EIRAS, JOSE ANTONIO; ZABOTTO, FABIO LUIS. Strain-induced modulation of magnetodielectric and magnetoelectric coupling in pzt/cfo thin films grown by rf-sputtering. Journal of Magnetism and Magnetic Materials, v. 552, p. 9-pg., 2022-02-25. (09/54082-2, 19/03110-8, 17/13769-1)

ALKATHY, MAHMOUD S.; EIRAS, J. A.; ZABOTTO, FABIO L.; RAJU, K. C. JAMES. Structural, optical, dielectric, and multiferroic properties of sodium and nickel co-substituted barium titanate ceramics. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, v. 32, n. 10, SI, JUL 2020. (19/03110-8)

ALKATHY, MAHMOUD S.; ZABOTTO, FABIO L.; RAJU, K. C. JAMES; EIRAS, J. A.. Effect of defects on the band gap and photoluminescence emission of Bi and Li co-substituted barium strontium titanate ceramics. Materials Chemistry and Physics, v. 275, JAN 1 2022. (19/03110-8)

ZABOTTO, F. L.; MILTON, P.; GUALDI, A. J.; DE OLIVEIRA, A. J. A.; EIRAS, J. A.; GARCIA, D.. Magnetodielectric and magnetoelectric correlation in (1-x)PMN-PT/xCFO 0-3 particulate composites. Journal of Alloys and Compounds, v. 829, JUL 15 2020. (09/54082-2, 19/03110-8, 17/24995-2, 13/07296-2)

ROSSI, VINICIUS PRETTI; BONINI, RICARDO PEREIRA; GONCALVES, ANDRE MARINO; GUALDI, ALEXANDRE JOSE; EIRAS, JOSE ANTONIO; ZABOTTO, FABIO LUIS. Silicon substrate orientation influence on structural and magnetic properties of BaFe12O19 thin films obtained by RF magneton sputtering. Journal of Magnetism and Magnetic Materials, v. 504, JUN 15 2020. (09/54082-2, 19/03110-8)

ALKATHY, MAHMOUD. S.; RAHAMAN, ATTAUR; MASTELARO, VALMOR R.; ZABOTTO, FABIO. L.; MILTON, FLAVIO PAULO; EIRAS, J. A.. Achieving high energy storage density simultaneously with large efficiency and excellent thermal stability by defect dipole, and microstructural engineering in modified-BaTiO3 ceramics. Journal of Alloys and Compounds, v. 934, p. 13-pg., 2023-02-10. (19/03110-8, 22/00821-3, 17/13769-1)

ALKATHY, MAHMOUD S.; LENTE, MANUEL H.; EIRAS, J. A.. Bandgap narrowing of Ba0.92Na0.04Bi0.04TiO3 ferroelectric ceramics by transition metals doping for photovoltaic applications. Materials Chemistry and Physics, v. 257, JAN 1 2021. (17/13769-1, 19/03110-8)

ALKATHY, MAHMOUD S.; EIRAS, J. A.; RAJU, K. C. JAMES. Energy storage enhancement and bandgap narrowing of lanthanum and sodium co-substituted BaTiO3 ceramics. Ferroelectrics, v. 570, n. 1, p. 153-161, JAN 2 2021. (19/03110-8)

ALKATHY, MAHMOUD. S.; ALI, SYED MANSOOR; GOUD, J. PUNDAREEKAM; MASTELARO, VALMOR R.; ZABOTTO, FABIO. L.; MILTON, FLAVIO PAULO; STRABELLO, ALEXANDRE; RAJU, K. C. JAMES; EIRAS, J. A.. Achieving dense microstructure with desired physical properties rapidly and inexpensively in Bi-modified SrTiO₃ ceramics via microwave sintering technique. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, v. 34, n. 22, p. 11-pg., 2023-08-01. (19/03110-8, 17/13769-1)

GOUD, J. PUNDAREEKAM; KUMAR, AJEET; ALKATHY, MAHMOUD S.; SANDEEP, KONGBRAILATPAM; RAMAN, AKHIL T. S.; SAHOO, BIBHUDATTA; RYU, JUNGHO; RAJU, K. C. JAMES. Thickness dependence of microwave dielectric tunability in Ba0 center dot 5Sr0 center dot 5TiO3 thin films deposited by pulsed laser deposition. CERAMICS INTERNATIONAL, v. 49, n. 1, p. 7-pg., 2022-11-24. (19/03110-8)

ALKATHY, MAHMOUD S.; ZABOTTO, FABIO. L.; MILTON, FLAVIO PAULO; BOTERO, ERITON RODRIGO; GATASHEH, MANSOUR K.; GOUD, J. PUNDAREEKAM; EIRAS, J. A.. Effect of sintering temperature on structural, electrical, and ferroelectric properties of neodymium and sodium co-doped barium titanate ceramics. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, v. 34, n. 14, p. 14-pg., 2023-05-01. (19/03110-8)

ALKATHY, MAHMOUD S.; ZABOTTO, FABIO L.; MILTON, FLAVIO PAULO; EIRAS, J. A.. Bandgap tuning in samarium-modified bismuth titanate by site engineering using iron and cobalt co-doping for photovoltaic application. Journal of Alloys and Compounds, v. 908, p. 10-pg., 2022-03-25. (19/03110-8, 17/13769-1)

ALKATHY, MAHMOUD S.; RAHAMAN, ATTAUR; MASTELARO, VALMOR R.; MILTON, FLAVIO PAULO; ZABOTTO, FABIO L.; LENTE, MANUEL H.; STRABELLO, ALEXANDRE; EIRAS, J. A.. Enhanced energy-storage density of BaTi0.95Zr0.05O3 via generation of defect dipoles upon lithium-doping. Materials Chemistry and Physics, v. 294, p. 12-pg., 2023-01-15. (19/03110-8, 22/00821-3, 17/13769-1)

ALKATHY, MAHMOUD S.; EIRAS, J. A.; ZABOTTO, FABIO L.; RAJU, K. C. JAMES. Structural, optical, dielectric, and multiferroic properties of sodium and nickel co-substituted barium titanate ceramics. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, v. 32, n. 10, p. 13-pg., 2020-07-10. (19/03110-8)