In situ evaluation of the lability of trace metals at Pantanal of Nhecolândia, MS, Brazil, using DGT technique with mixed binding layer for simultaneouse determination of cations e anions

• Grant number: 19/07359-0
• Support Opportunities: Scholarships in Brazil - Doctorate
• Effective date (Start): August 01, 2019
• Effective date (End): February 28, 2023
• Field of knowledge: Physical Sciences and Mathematics - Chemistry - Analytical Chemistry
• Principal Investigator: Amauri Antonio Menegário
• Grantee: Carlos Eduardo Eismann
• Host Institution: Centro de Estudos Ambientais (CEA). Universidade Estadual Paulista (UNESP). Campus de Rio Claro. Rio Claro , SP, Brazil
• Associated research grant: 16/14227-5 - Climatic changes and environmental impacts in wetlands of Pantanal region (Brazil): quantification, control factors and long term temporal modeling, AP.PFPMCG.TEM

Abstract

At the Pantanal of Nhecolandia region, a diversity of lakes with a wide variety of biogeochemical and hydrological conditions and a complex system of saline and alkaline lakes with singular characteristics, which its biogeochemical behavior is just partially understood. Identifying and quantifying the labile concentrations give valuable information about the diverse and complex biogeochemical processes that influence the biogeoavailability of a given chemical element. The DGT (Diffusive Gradients in Thin Films) technique is widely used in studies about the availability of trace elements at the natural environment. The present work intends to evaluate in situ the labile concentrations of trace elements present at the waters of Nhecolândia lakes with different characteristics (green, black and crystalline waters) using DGT devices with mixed binging layer for the simultaneous determination of cations and anions. Previous experiments will be performed aiming the optimization of the methods to allow its effective use under the challenging conditions to be found at the in situ studies. The determination and quantification of the simples will be performed at the Environmental Studies Center (CEA) of the UNESP of Rio Claro using Inductively Coupled Plasma Mass Spectrometry (ICP-MS). The present work intends to complement the researches developed at the projeto temático (16/14227-5) and projeto regular (2018/17069-7) supported by FAPESP. (AU)

Scientific publications

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

VIANA, JOSE LUCAS MARTINS; DE SOUZA, ADRIANA FELIX; HERNANDEZ, AMAURIS HECHAVARRIA; ELIAS, LUCAS PELLEGRINI; EISMANN, CARLOS EDUARDO; REZENDE-FILHO, ARY TAVARES; BARBIERO, LAURENT; MENEGARIO, AMAURI ANTONIO; FOSTIER, ANNE HELENE. In situ arsenic speciation at the soil/water interface of saline-alkaline lakes of the Pantanal, Brazil: A DGT-based approach. Science of The Total Environment, v. 804, JAN 15 2022. (16/14227-5, 18/17069-7, 19/18124-4, 19/07359-0)

EISMANN, CARLOS EDUARDO; MENEGARIO, AMAURI ANTONIO; DE OLIVEIRA JR, EDSON GERALDO; ELIAS, LUCAS PELLEGRINI; VIANA, JOSE LUCAS MARTINS; ZANATTA, MELINA BORGES TEIXEIRA; BARBIERO, LAURENT; FOSTIER, ANNE HELENE. A simple, green and low-cost agarose-based binding layer for simultaneous determination of cations and anions in aquatic systems using DGT. ANALYTICAL METHODS, v. 15, n. 27, p. 9-pg., 2023-06-23. (18/17069-7, 19/18124-4, 16/14227-5, 22/00518-9, 19/07359-0, 21/14272-9)