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Universidade Estadual de Campinas (UNICAMP). Instituto de Química (IQ) (Institutional affiliation from the last research proposal) Birthplace: Brazil
Caio Costa Oliveira in research grants and scholarships supported by FAPESP.
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Catalytic methods for the synthesis of enantiomerically pure compounds are of great importance for the preparation of pharmacologically active substances and for Fine Chemicals. The rational development of enantioenriched ligands allows the preferential preparation of one of the two enantiomeric products in reactions catalyzedby transition metals. The main topic of this research project i…
RuCl2(p-cymene)]2 catalyst is the more widely employed ruthenium source in C-H functionalization. Recently, ruthenacycles were reported as efficient catalyst foralkylation and arylation reactions under mild conditions In both cases, catalyticsystems provide non chiral products.Herein, we aim to develop a methodology of enantioselective C-H activationcatalyzed by ruthenium . For this new r…
The main idea of the present project is developing a method of remote functionalization via monotransposition of terminal olefins, catalyzed by nickel. This project is going to be a continuation of the initial work, which involves the terminal alkene isomerization, under kinetic control, exploring the reactivity not only of the product formed during the process, but also the À-allyl nicke…
This PhD project, in force since 2019, focuses on the synthesis of ligands and formation of enantioenriched metal complexes and their catalytic activity. From the beginning, the object of study was the class of nitrogenous ligands, specifically the bispyridines. The initial objective was the synthesis of bifunctional ligands, capable of containing two different metals in order to perform …
(Only some records are available in English at this moment)
Asymmetric transition metal-catalyzed cross-coupling reactions are pivotal C-C bondformingprocesses in organic synthesis. In the PhD currently in progress in Brazil we havesynthesized Ruthenium complexes bearing oxazoline ligands and evaluated theirapplication in C-H arylation and C-H alkylation reactions - using aryl halides, iodoniumsalts and olefins, respectively. In this proposal, we …
The first examples of the enantioselective Heck-Matsuda reaction were describedrecently by the group of Professor Correia. In spite of the good yields andenantiodiferentiation achieved for the desymmetrization of olefins using C2 symmetricbisoxazolines, the regioselective arylation of non-symmetrical substrates still remains adifficult task. To circumvent this problem we propose in this p…
| 1 / 1 | Completed research grants |
| 9 / 9 | Completed scholarships in Brazil |
| 1 / 1 | Ongoing scholarships abroad |
| 1 / 1 | Completed scholarships abroad |
| 12 / 12 | All research grants and scholarships |
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