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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Simultaneous determination of Cu, Pb, Cd, Ni, Co and Zn in bioethanol fuel by adsorptive stripping voltammetry and multivariate linear regression

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Author(s):
Nascimento, Danielle S. [1] ; Insausti, Matias [2] ; Band, Beatriz S. F. [3] ; Lemos, Sherlan G. [4]
Total Authors: 4
Affiliation:
[1] Univ Fed Paraiba. Dept Quim
[2] Univ Nacl Sur. Dept Quim
[3] Univ Nacl Sur. Dept Quim
[4] Univ Fed Paraiba. Dept Quim
Total Affiliations: 4
Document type: Journal article
Source: FUEL; v. 137, p. 172-178, DEC 1 2014.
Web of Science Citations: 0
Abstract

In this work it is proposed the one-voltammogram simultaneous determination of Cu(II), Pb(II), Cd(II), Ni(II), Co(II), and Zn(II) at ppb and sub-ppb levels in bioethanol fuel samples by adsorptive stripping voltammetry. Mixed ligands were employed providing stripping peaks for all analytes at the same voltammetric scan under optimized conditions. To perform the determination, multivariate linear regression aided by successive projections algorithm (SPA-MLR) was evaluated. The voltammograms were preprocessed with the asymmetric least squares (AsLS) baseline correction algorithm and the icoshift peak alignment tool. An excellent analytical performance was obtained, despite the inherent complexity of the simultaneous determination, with average apparent recovery = 96% +/- 16%, and better prediction results in comparison with the benchmark method of partial least squares (PLS). (C) 2014 Elsevier Ltd. All rights reserved. (AU)

FAPESP's process: 08/57808-1 - National Institute of Advanced Analytical Science and Technology
Grantee:Celio Pasquini
Support type: Research Projects - Thematic Grants