Combination of photoelectrocatalysis and ozonation: A novel and powerful approach applied in Acid Yellow 1 mineralization

Author(s)

Bessegato, Guilherme Garcia ^[1] ; Cardoso, Juliano Carvalho ^[1] ; da Silva, Bianca Ferreira ^[1] ; Boldrin Zanoni, Maria Valnice ^[1]

Affiliation

^[1] Univ Estadual Paulista Julio de Mesquita Filho UN, Inst Chem, Dept Analyt Chem, BR-14800060 Araraquara, SP - Brazil

• Document type: Journal article
• Source: APPLIED CATALYSIS B-ENVIRONMENTAL; v. 180, p. 161-168, JAN 2016.
• Web of Science Citations: 30

Abstract

Photoelectrocatalytic oxidation (PEC) is known to be a powerful technique employed with the aim of promoting organic degradation. Its efficiency is nonetheless found to be dramatically decreased when applied in highly concentrated effluent treatment owing to the reduced transparency which minimizes the photons reaching the semiconductor surface. In light of that, the present work seeks to describe a novel combination of photoelectrocatalysis and ozonation (O-3 + PEC) techniques, aiming at achieving a faster decolorization of a highly concentrated solution and a higher rate of mineralization. The Acid Yellow 1 dye (AYI), widely used in cosmetics was chosen as a colorful solution model. TiO2 nanotubes electrode was used as photoanode in an annular bubble reactor operating at 2.0 V with UV-B irradiation in the presence of 1.25 x 10(-4) mol min(-1) of O-3. The main factors interfering in the O-3 + PEC process were optimized through UV/vis spectrophotometry, total organic carbon (TOC) and mass spectrometry measurements. After 20 min of treatment using the combined system, 100% of decolorization was observed while a total mineralization was seen following 60 min of treatment even in effluents containing 100 ppm AY1. Concomitantly, the combined system (O-3+ PEC) showed higher decolorization rate constant and lower energy consumption compared to the other techniques, showing that O-3 + PEC is a successful, efficient and cost-effective alternative for water treatment. (C) 2015 Elsevier B.V. All rights reserved. (AU)

• FAPESP's process: 14/03679-7 - Degradation of hair dyes and salon wastewater by photoelectrocatalysis with modified TiO2 nanotube electrodes and combination with ozonation
• Grantee: Guilherme Garcia Bessegato
• Support Opportunities: Scholarships in Brazil - Doctorate (Direct)
• FAPESP's process: 08/10449-7 - Assessment of occurrence, toxicity/genotoxicity and degradation processes of dyes in effluents and surface water
• Grantee: Maria Valnice Boldrin
• Support Opportunities: Research Projects - Thematic Grants