Synthesis of BaTIO3 and SrTIO3 by microwave assisted hidrotermal method (mah) using anatase as titanium precursor

Author(s)

Renata S. Magalhães ^[1] ; Wagner D. M. Junior ^[2] ; Agda E. Souza ^[3] ; Silvio R. Teixeira ^[4] ; Máximo S. Li ^[5] ; Elson Longo ^[6]

Affiliation

^[1] Universidade Estadual Paulista. Departamento de Física - Brasil

^[2] Universidade Estadual Paulista. Departamento de Física - Brasil

^[3] Universidade Estadual Paulista. Departamento de Física - Brasil

^[4] Universidade Estadual Paulista. Departamento de Física - Brasil

^[5] Universidade de São Paulo. Instituto de Física de São Carlos - Brasil

^[6] Universidade Estadual Paulista. Instituto de Química - Brasil

• Document type: Journal article
• Source: Química Nova; v. 40, n. 2, p. 166-170, 2017-02-00.

Abstract

In this work barium titanate (BT) and strontium titanate (ST) were prepared by Microwave-Assisted Hydrothermal (MAH) method, using a Ti precursor different from those shown in the literature and various concentrations (1, 3 e 6 mol L-1) of KOH mineralizer. As a titanium precursor, an anatase complex with hydrogen peroxide were used. For the precursors of barium and strontium, chlorides were used. The materials resulting from the synthesis processes were characterized in room temperature by different techniques as like: X-Ray Diffraction (XRD), micro-Raman Spectroscopy, UV-Vis, Scanning Electron Microscopy (SEM) and Photoluminescence (PL). The results show that there were differences in crystallinity, morphology, number of phases and photoluminescence depending on the concentration of the mineralizer. (AU)

• FAPESP's process: 13/07296-2 - CDMF - Center for the Development of Functional Materials
• Grantee: Elson Longo da Silva
• Support Opportunities: Research Grants - Research, Innovation and Dissemination Centers - RIDC