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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Excess volumes and partial molar volumes of binary liquid mixtures of furfural or 2-methylfuran with alcohols at 298.15 K

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Author(s):
Follegatti-Romero, L. M. [1] ; Sosa, F. H. B. [2] ; Costa, M. C. [2] ; Tavares, D. T. [3] ; de Oliveira, L. H. [4] ; Follegatti-Romero, L. A. [3]
Total Authors: 6
Affiliation:
[1] UNAS, FIIA, Tingo Maria, Hco - Peru
[2] State Univ Campinas UNICAMP, Lab Phase Equilibrium LEF, Sch Chem Engn FEQ, Campinas, SP - Brazil
[3] Univ Sao Paulo, LPESF, Dept Chem Engn PQI, Polytech Sch EP, Sao Paulo, SP - Brazil
[4] State Univ Maringa UEM, Lab Adsorpt & Ion Exchange LATI, Dept Chem Engn DEQ, Maringa, Parana - Brazil
Total Affiliations: 4
Document type: Journal article
Source: JOURNAL OF CHEMICAL THERMODYNAMICS; v. 134, p. 20-30, JUL 2019.
Web of Science Citations: 0
Abstract

In this work, densities, excess molar volumes, partial molar volumes and excess partial molar volumes for binary liquid mixtures of furfural and 2-methylfuran with 1-propanol or 2-propanol or 2-butanol or 1-pentanol or 2-pentanol or 1-hexanol at 298.15 K and 0.1 MPa over the entire range of composition were determined. Excess molar volumes were correlated with Redlich-Kister equation with average absolute deviations smaller than 0.0164. Excess molar volumes were negative for furfural + 1-propanol or 2-propanol and positive for all other studied binary systems. Solute partial molar volumes determined increase as alcohol carbon chain length increase, except for furfural + 2-pentanol, which presented smaller values than 2-butanol for molar fractions below 0.2. A maximum/minimum was observed from the excess partial molar volume plots. FTIR spectra data indicate bands at 3135 cm(-1), for furfural systems, and 3122 cm(-1) for 2-methylfuran systems, are related to the behavior found for excess molar volumes and that H-bonds are smaller for furfural systems than for 2-methylfuran. (C) 2019 Elsevier Ltd. (AU)

FAPESP's process: 16/05950-5 - Liquid-liquid Equilibrium in the Production of Furanic Compounds
Grantee:Luis Alberto Follegatti Romero
Support type: Regular Research Grants
FAPESP's process: 12/05027-1 - Solid-liquid equilibrium of fatty compounds and biodiesel flash point
Grantee:Mariana Conceição da Costa
Support type: Program for Research on Bioenergy (BIOEN) - Young Investigators Grants
FAPESP's process: 14/21252-0 - Equilibrium and production processes of biofuels and bioproducts
Grantee:Antonio José de Almeida Meirelles
Support type: Research Projects - Thematic Grants