Layer-by-Layer nanostructured films of magnetite nanoparticles and polypyrrole towards synergistic effect on methylparaben electrochemical detection

Author(s)

de Lima, Lucas F. ^[1] ; Daikuzono, Cristiane M. ^[1] ; Miyazaki, Celina M. ^[1] ; Pereira, Elisabete A. ^[1] ; Ferreira, Marystela ^[1]

Affiliation

^[1] Fed Univ Sao Carlos UFSCar, Ctr Sci & Technol Sustainabil CCTS, BR-18052780 Sorocaba, SP - Brazil

• Document type: Journal article
• Source: Applied Surface Science; v. 505, MAR 1 2020.
• Web of Science Citations: 2

Abstract

The sustained use of cosmetics, hygiene products and medicines containing methylparaben (MeP) can be related to cases of cancer in women and children, which is why it is important to develop simple ways to monitor this compound. Gold electrodes were modified with Layer-by-Layer (LbL) films of magnetite nanoparticles (MNP) and polypyrrole (Ppy) for electrochemical determination of MeP. To investigate the synergistic effect between the MNP and Ppy, three different LbL architectures were tested: multilayers of Ppy with an conventional polycation poly(allylamine hydrochloride) - Au/(PAH/Ppy)(3), MNP with a conventional polyanion poly(vinyl sulfonic acid)- Au/(MNP/PVS)(3) and the hybrid composite film Au/(MNP/Ppy)(3). The highest oxidation current and lowest oxidation potential were achieved by the Au/(MNP/Ppy)(3) electrode in a range up to 131.4 mu mol L-1 with a limit of detection of 9.95 x 10(-8) mol L-1. The performance of the electrochemical sensor was statistically investigated by the Miller-Miller method demonstrating accuracy comparable to an analytical method (capillary electrophoresis). MeP was determined in urine, breast milk and cosmetic with recovery values varying from 84.0% to 113.3%. (AU)

• FAPESP's process: 14/15093-7 - Study of nanostructured systems by surface plasmon resonance (SPR): applications in biosensing
• Grantee: Celina Massumi Miyazaki
• Support Opportunities: Scholarships in Brazil - Post-Doctoral
• FAPESP's process: 18/04061-8 - Layer by layer films of polypyrrol and magnetite nanoparticles in the analytical determination of parabens
• Grantee: Lucas Felipe de Lima
• Support Opportunities: Scholarships in Brazil - Master
• FAPESP's process: 16/19387-0 - LbL (LAYER-BY-LAYER) and Langmuir-Blodgett (LB) nanostructured films with emodin for systems carriers.
• Grantee: Marystela Ferreira
• Support Opportunities: Regular Research Grants
• FAPESP's process: 11/23286-1 - Analytical and environmental studies of the spatial, seasonal and temporal distribution of the low molar weight aldehydes in the atmosphere of the Sorocaba region
• Grantee: Elisabete Alves Pereira
• Support Opportunities: Regular Research Grants