| Full text | |
| Author(s): |
Stivanin, Mateus L.
[1]
;
Gallo, Rafael D. C.
[1]
;
Spadeto, Joao Paulo M.
[1]
;
Cormanich, Rodrigo A.
[1]
;
Jurberg, Igor D.
[1]
Total Authors: 5
|
| Affiliation: | [1] Univ Estadual Campinas, Inst Chem, Rua Monteiro Lobato 270, BR-13083862 Campinas, SP - Brazil
Total Affiliations: 1
|
| Document type: | Journal article |
| Source: | ORGANIC CHEMISTRY FRONTIERS; v. 9, n. 5, p. 1321-1326, MAR 1 2022. |
| Web of Science Citations: | 0 |
| Abstract | |
A blue light-promoted reaction between aryldiazoacetates and different nucleophiles has been developed in the presence of THF (and other cyclic ethers) as the solvent, allowing the incorporation of these three elements into a single product. Formally, this transformation represents an O-H insertion strategy of more complex alcohols into aryldiazoesters, without the need of pre-assembling them. The method is mild and efficient and proceeds in the absence of metals, generally at room temperature. (AU) | |
| FAPESP's process: | 20/00144-6 - Structural proteomics: design, synthesis and application of new generation crosslinking agents |
| Grantee: | Rafael Douglas Clemente Gallo |
| Support Opportunities: | Scholarships in Brazil - Post-Doctoral |
| FAPESP's process: | 20/06536-3 - Fluorinase reactive substrate analysis |
| Grantee: | João Paulo Menezes Spadeto |
| Support Opportunities: | Scholarships in Brazil - Master |
| FAPESP's process: | 18/03910-1 - Physicochemical studies of fluorinated organic compounds: experimental and theoretical approaches |
| Grantee: | Rodrigo Antonio Cormanich |
| Support Opportunities: | Research Grants - Young Investigators Grants |
| FAPESP's process: | 19/01235-8 - Photochemistry with visible light using donor-acceptor diazocompounds |
| Grantee: | Igor Dias Jurberg |
| Support Opportunities: | Regular Research Grants |