One-step preparation of Co2V2O7: synthesis and application as a Fenton-like catalyst in a gas diffusion electrode

Author(s)

Gromboni, Murilo Fernando ; Marques Cordeiro-Junior, Paulo Jorge ; Corradini, Patricia Gon ; Mascaro, Lucia Helena ; de Vasconcelos Lanza, Marcos Roberto

• Document type: Journal article
• Source: Physical Chemistry Chemical Physics; v. 24, n. 17, p. 14-pg., 2022-03-30.

Abstract

Bimetallic oxides and MOFs have been used as catalysts for the ORR via two-electron and Fenton-based processes. This work reports the development of a new green one-step route for obtaining Co2V2O7. The Co2V2O7 oxide was immobilized on Printex-L6 carbon and used as a catalyst for the oxygen reduction reaction (ORR) and in heterogeneous Fenton-based processes. The PL6C/2.5% Co2V2O7 sample exhibited the best performance in the ORR via a two-electron pathway, increasing the selectivity for H2O2 generation. Electrochemical impedance spectroscopy analysis showed a decrease in charge transfer resistance in the Co2V2O7/PL6C matrix. The application of a gas diffusion electrode (GDE) modified with 2.5% Co2V2O7 resulted in a 30% increase in H2O2 production compared to the unmodified GDE. The unmodified GDE promoted methyl-paraben (MeP) removal of similar to 80% after 90 min treatment, whereas the modified GDE promoted similar to 90% of MeP removal in 30 min. The results obtained point to the potential of Co2V2O7 in improving the efficiency of GDE when applied for the treatment of organic pollutants. (AU)

• FAPESP's process: 19/00288-0 - Degradation of antibiotics by electrochemical advanced oxidation processes
• Grantee: Murilo Fernando Gromboni
• Support Opportunities: Scholarships in Brazil - Post-Doctoral
• FAPESP's process: 18/16401-8 - Photocatalysts and photoelectrodes for obtaining renewable fuels
• Grantee: Lucia Helena Mascaro Sales
• Support Opportunities: Regular Research Grants
• FAPESP's process: 17/10118-0 - Study and application of electrochemical technology for the analysis and degradation of endocrine interferents: materials, sensors, processes and scientific dissemination
• Grantee: Marcos Roberto de Vasconcelos Lanza
• Support Opportunities: Research Projects - Thematic Grants
• FAPESP's process: 14/50945-4 - INCT 2014: National Institute for Alternative Technologies of Detection, Toxicological Evaluation and Removal of Micropollutants and Radioactivies
• Grantee: Maria Valnice Boldrin
• Support Opportunities: Research Projects - Thematic Grants
• FAPESP's process: 14/50249-8 - Green chemistry: sustainable synthetic methods employing benign solvents, safer reagents, and bio-renewable feedstock
• Grantee: Arlene Gonçalves Corrêa
• Support Opportunities: Research Grants - Research Centers in Engineering Program
• FAPESP's process: 16/19612-4 - Degradation of endocrine disruptors carbofuran, methylparaben and propylparaben via electrogenerated H2O2 and associated processes (electrogenerated H2O2/UV, electro-Fenton e photoelectro-Fenton)
• Grantee: Paulo Jorge Marques Cordeiro Junior
• Support Opportunities: Scholarships in Brazil - Doctorate (Direct)