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Influence of Zr addition in β Ti-25Ta-xZr alloys on oxide formation by MAO-treatment

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Author(s):
Kuroda, Pedro A. B. ; dos Santos, Rafael F. M. ; Rossi, Mariana C. ; Correa, Diego R. N. ; Grandini, Carlos R. ; Afonso, Conrado R. M.
Total Authors: 6
Document type: Journal article
Source: VACUUM; v. 217, p. 12-pg., 2023-09-01.
Abstract

Titanium and its alloys are widely used in the biomedical field, as they have good mechanical properties for use in orthopedics. However, a surface that promotes bone tissue growth is desired. Although titanium is considered a bioactive element due to its thin layer of passive titanium dioxide, such characteristics can be improved to optimize its surface properties. This study aims to develop the Ti-25Ta-xZr system alloys (x = 0, 25, and 50% by weight) and perform a surface modification, micro-arc oxidation, to increase the bulk protection layer, create a porous layer and incorporate bioactive elements on the surface. The alloys had different phases (alpha", alpha"+beta, and beta), and the surface modification process was able to incorporate calcium, phosphorus, and magnesium. In addition, the X-ray diffraction technique and XPS detected the crystalline phases of the respective alloying elements ox-ides. In this study, adding zirconium increased the amount of the beta phase of "Ti-25Ta" and the surface layer, increased the number of pores, decreased the pore area, and reduced the surface roughness. (AU)

FAPESP's process: 21/03865-9 - Influence of surface modifications on bioactivity and (tribo) corrosion of beta Ti-Nb-(Zr) alloys with low elastic modulus for application as implant
Grantee:Mariana Correa Rossi
Support Opportunities: Scholarships in Brazil - Post-Doctoral
FAPESP's process: 18/18293-8 - Titanium alloys: phase transformations and additive manufacturing applied to obtaining functionally graded materials
Grantee:Rubens Caram Junior
Support Opportunities: Research Projects - Thematic Grants
FAPESP's process: 19/26517-6 - Influence of the microstructure and phases on surface functionalization of beta Ti-25Ta-xZr- alloys system
Grantee:Pedro Akira Bazaglia Kuroda
Support Opportunities: Scholarships in Brazil - Post-Doctoral