Synthesis and characterization of CuO-MgO-ZnO and CuO-Co₃O₄-CeO₂

Author(s)

Dias, Leonardo Francisco Goncalves ; Pimentel, Gabriel Junior Cavalcante ; Rheinheimer, Joao Pedro Costa ; Gomes, Orisson Ponce ; de Almeida, Bianca Gottardo ; Volanti, Diogo Paschoalini ; de Almeida, Margarete Teresa Gottardo ; Lisboa-Filho, Paulo Noronha

• Document type: Journal article
• Source: DISCOVER MATERIALS; v. 3, n. 1, p. 12-pg., 2023-09-26.

Abstract

The synthesis of trioxides offers unique properties for different applications due to the combination of multiple oxides; however, few studies have reported on the properties of these materials, especially in terms of their ability to create reactive oxygen species, which are helpful for antibacterial and antifungal activity. This study aimed to evaluate the surface properties of CuO-MgO-ZnO and CuO-Co3O4-CeO2 trioxides synthesized via precipitation assisted by an ultrasonic bath or sonication. The structural analysis indicated the formation of micrometric particles consisting of individual phases of each oxide, with no apparent influence of the preparation method on their morphology. UV-Vis spectroscopy revealed that CuO-MgO-ZnO particles have a band gap near 5.5 eV, while CuO-Co3O4-CeO2 has a single value at 4.2 eV. Zeta potential measurements indicated changes in the materials' outermost layer composition due to the synthesis method. Additionally, biological assays showed that the materials could completely inhibit the growth of Candida species and Staphylococcus aureus but not Klebsiella pneumoniae. These results suggest that the materials may be suitable for self-cleaning surfaces and medical device coatings. (AU)

• FAPESP's process: 19/09431-0 - Hemocompatible materials with surfaces modified by zwitterionic molecules
• Grantee: Orisson Ponce Gomes
• Support Opportunities: Scholarships in Brazil - Doctorate
• FAPESP's process: 20/06421-1 - Development of sensors derived from metal-organic frameworks to detect microbial volatile organic compounds
• Grantee: Diogo Paschoalini Volanti
• Support Opportunities: Regular Research Grants
• FAPESP's process: 18/07520-3 - Immobilization of bisphosphonates on nanostructured surface films of TiO2 and hydroxyapatite
• Grantee: Leonardo Francisco Gonçalves Dias
• Support Opportunities: Scholarships in Brazil - Doctorate (Direct)