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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Iron(III) chloride catalyzed glycosylation of peracylated sugars with allyl/alkynyl alcohols

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Author(s):
Narayanaperumal, Senthil [1] ; da Silva, Rodrigo Cesar [1] ; Monteiro, Julia L. [1] ; Correa, Arlene G. [1] ; Paixao, Marcio W. [1]
Total Authors: 5
Affiliation:
[1] Univ Fed Sao Carlos, Dept Quim, BR-13565905 Sao Carlos, SP - Brazil
Total Affiliations: 1
Document type: Journal article
Source: Journal of the Brazilian Chemical Society; v. 23, n. 11, p. 1982-1988, NOV 2012.
Web of Science Citations: 2
Abstract

In this work, the use of ferric chloride as an efficient catalyst in glycosylation reactions of sugars in the presence of allyl and alkynyl alcohols is described. The corresponding glycosides were obtained with moderate to good yields. This new procedure presented greater selectivity when compared to classic methods found in the literature. Principal features of this simple method include non-hazardous reaction conditions, low-catalyst loading, good yields and high anomeric selectivity. (AU)

FAPESP's process: 09/07281-0 - Asymmetric organocatalysis: design of new organocatalysts and development of new methodologies
Grantee:Márcio Weber Paixão
Support Opportunities: Research Grants - Young Investigators Grants