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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Thermal and spectroscopic studies on solid ibuprofen complexes of lighter trivalent lanthanides

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Galico, D. A. [1] ; Holanda, B. B. C. [1] ; Guerra, R. B. [1] ; Legendre, A. O. [1] ; Rinaldo, D. [1] ; Treu-Filho, O. [2] ; Bannach, G. [1]
Total Authors: 7
[1] UNSEP Univ Estadual Paulista, Fac Ciancias, Dept Quim, BR-17033260 Sao Paulo - Brazil
[2] UNSEP Univ Estadual Paulista, Inst Quim, BR-14800900 Sao Paulo - Brazil
Total Affiliations: 2
Document type: Journal article
Source: Thermochimica Acta; v. 575, p. 226-232, JAN 10 2014.
Web of Science Citations: 13

Solid-state compounds of general formula Ln(L)(3), in which Lis ibuprofen and Ln stands for trivalent La, Ce, Pr, Nd, Sm and Eu, have been synthesized. Simultaneous thermogravimetry and differential thermal analysis (TG-DTA), X-ray powder diffractometry (DRX), complexometry, Fourier-transformed infrared spectroscopy (FTIR) and thermogravimetry coupled to Fourier-transformed infrared spectroscopy (TG-FTIR) were used to characterize these compounds. The results provided information concerning the chemical composition, dehydration, coordination modes of the ligands, crystallinity of the samples, thermal behavior and thermal decomposition of the compounds. The theoretical and experimental spectroscopic studies suggest that ibuprofen coordinates through the carboxylate group as a chelating ligand. (C) 2013 Elsevier B.V. All rights reserved. (AU)

FAPESP's process: 12/21450-1 - Thermoanalytical studies, synthesis and characterization of the solid co-crystals of ketoprofen with some co-formers
Grantee:Gilbert Bannach
Support type: Regular Research Grants